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How are the so-very-successful Internet standards produced The success of the Internet is attributable to its excellent standards, and this excellence is the result of a standards process that has been carefully developed over the years, starting with Request for Comments (RFC) number 1, Host Software, by Steve Crocker published on April 7, 1969. One notable distinction of the Internet standards process is its complete openness everything is available online at all times and without cost to everyone who may be interested. Online participation in the standards development is open to anyone who feels qualified to contribute. Another notable distinction is that standards are proposed and developed by individual contributors and not by organizations or corporate entities. To quote freely Fred Baker from Cisco, a former chair of the IETF: Make sure you represent your own opinion, so that you don t have to change it if you change jobs. We also observe the predominance of computer scientists from research and academia in the Internet standards community, people who are less processoriented, but have a keen sense and hands-on knowledge of networks and computing. The Internet standards process at present is best described in reference [7]. In a nutshell, the goals of the Internet standards process are as follows:



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Appendix B: Core ADSI Reference . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 747

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As noted earlier, a number of cyclopentadienyl metal-containing polymers have been synthesized. In some cases, the Cp has been substituted. In general when the substitution is organic, such as replacing the ve Cp-hydrogens with methyl groups, the resulting products possess increased steric bulk; more electron-donating ablity; and have more organic-like properties, including greater solubility in organic solvents. The electron donating nature of the methyl group makes the resulting pentamethyl-Cp a stronger- eld ligand than Cp itself. Thus (Me5Cp)2Mn is low spin in contrast to Cp2Mn. The visible spectra of most (Me5Cp)2M compounds show greater splitting between the 2a1g and 2e1g orbitals. Physical constants related to the electron density on the metal are also generally greater for the substituted Cp complexes. This electron buildup makes the substituted-Cp compound easier to oxidize than the corresponding nonsubstituted Cp. The reduction potential is often shifted by 0.5 V for such compounds.25 The combination of steric hindrance and a greater gap between HOMOs and LUMOs gives organic-substituted Cp-compounds greater kinetic and thermal stability relative to Cp itself. C5H 5 1 is essentially an 5 ligand donating six electrons. The general term metallocene is used to describe these bis(cyclopentadienyl) metal complexes. The most heavily studied metallocene is ferrocene. In the MO treatment of ferrocene, the a1 frontier orbital and all lower orbitals are full, but the e1 and all higher orbitals are empty. These frontier orbitals are considered to be neither strongly bonding nor strongly antibonding. This characteristic

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The kinetics of the esterification of 1-octanol with hexanoic acid on zeolite BEA was studied by Nijhuis et al. [29]. For the acid, a first-order behavior was found, whereas the alcohol showed a negative reaction order of 1. From the data, an Eley Rideal mechanism was concluded. The acid adsorbs onto the surface of the catalyst and reacts with an alcohol. The adsorption of water, alcohol, ester or ether inhibits the reaction. Hoek [30] found that the adsorption constant of water is more than one order of magnitude higher than those of the other compounds. The rate law given by Nijhuis et al. [29] also includes the equilibrium limitation:

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