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The product cx-olefins formed in the oligomerization of ethylene induced by a Ni catalyst with phosphine ligands is not soluble in l,4-butanediol applied as solvent but separates and is decanted Appropriately modified water-soluble ligands, specifically, sulfonated triphenylphosphines, are applied in the hydroformylation process A new type of ligands, namely, water-soluble Ir and Rh complexes with tris(hydroxymethyl)phosphine 115 and a cationic sugar-substituted Rh complex, 116 have been described for hydroformylation Aqueous biphasic catalysis is also used in homogeneous hydrogenations I17 - 119 In new examples Ru clusters with the widely used TPPTN [tris(3-sulfonatophenyl) phosphine] ligand 120 and Rh complexes with novel carboxylated phosphines 121 were applied in alkene hydrogenation, whereas Ru catalysts were used in the hydrogenation of aromatics 122,123 Aerobic oxidation of terminal alkenes to methyl ketones was carried out in a biphasic liquid-liquid system by stable, recyclable, water-soluble Pd(II) complexes with sulfonated bidentate diamine ligands.



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s i g n a l ball-y-t , ball-y-b : unsigned (9 downto 0 ) ; reg t o t r a c k l e f t , t o p boundary s i g n a l ball-x-reg , ball-x-next : unsigned ( 9 downto 0 ) ;

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124 Fluorous biphasic catalysis is a rapidly developing alternative Since the initial archival publication by Horvath and Rabai 125 indicating the tremendous potential of this approach, many homogeneous catalytic reactions were carried out in fluorous biphasic system 126-132 In this case, the homogeneous catalyst is modified with long-chain fluoroponytails to render them soluble in the fluorous phase To overcome the high electron-withdrawing character of the perfluoroalkyl group attached to the metal center, which may alter electronic properties and reactivities of the.





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Key or Key Combination Tab Shift+Tab Function Moves to the next field Moves to the previous field Moves up one line in the current multiline field or to the beginning of a single-line field or one where you re already on the first line Moves down to the next line in the current multiline field or to the end of a single-line field or one where you re already on the last line Moves one character position left in the current field, if possible; otherwise, does nothing Moves one character position right in the current field, if possible; otherwise, does nothing

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n(x,t ) = R-1'2

Figure 4.5 Global ocean currents. (Reprinted from Schlesinger, W.H. 1997. Biogeochemistry: An analysis of global change, 2nd edn. Academic Press, New York. Copyright 1997, with permission from Elsevier.)

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FIGURE 13.1 You can select Show Custom Dialog from the Miscellaneous group of commands in the Edit Script window.

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