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When the light emitted by the gas is passed through a prism or a diffraction grating, the emission spectrum of an atom is obtained An emission spectrum can be studied in greater detail using an instrument called a spectroscope As shown in Figure 28-4a, light in a prism spectroscope passes through a slit and is then dispersed as it travels through a prism A lens system (not shown in the diagram) focuses the dispersed light so that it can be viewed, or recorded on a photographic plate or an electronic detector The spectroscope forms an image of the slit at a different position for each wavelength The spectrum of a hot body, or incandescent solid, such as the filament in a lightbulb, is a continuous band of colors from red through violet The spectrum of a gas, however, is a series of distinct lines of different colors The bright-line emission spectra for mercury gas and barium gas are shown in Figure 28-4b and Figure 28-4c, respectively Each colored line corresponds to a particular wavelength of light emitted by the atoms of that gas An emission spectrum is also a useful analytic tool, as it can be used to identify an unknown sample of gas When the unknown gas is placed in a gas-discharge tube, it can be made to emit light The emitted light consists of wavelengths that are uniquely characteristic of the atoms of that gas Thus, the unknown gas can be identified by comparing its wavelengths with the wavelengths present in the spectra of known samples An emission spectrum also can be used to analyze a mixture of gases When the emission spectrum of a combination of elements is photographed, an analysis of the lines on the photograph can indicate the identities and the relative concentrations of the elements present If the material being examined contains a large amount of any particular element, the lines for that element are more intense on the photograph than those of the other elements of lesser quantities Through a comparison of the line intensities, the percentage composition of the material can be determined.



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Figure 28-5 Fraunhofer lines appear in the absorption spectrum of the Sun There are many lines, some of which are faint and others that are very dark, depending on abundances of the elements in the Sun





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Absorption spectra In 1814, Josef von Fraunhofer observed the presence of several dark lines in the spectrum of sunlight These dark lines, now called Fraunhofer lines, are seen in Figure 28-5 He reasoned that as sunlight passed through the gaseous atmosphere surrounding the Sun, the gases absorbed certain characteristic wavelengths These absorbed wavelengths produced the dark lines in the observed spectrum The set of wavelengths absorbed by a gas is the absorption spectrum of the gas The composition of the Sun s atmosphere was determined by comparing the missing lines in the observed spectrum with the known emission spectra of various elements The compositions of many other stars have been determined using this technique You can observe an absorption spectrum by passing white light through a gas sample and a spectroscope, as shown in Figure 28-6a Because the gas absorbs specific wavelengths, the normally continuous spectrum of the white light has dark lines in it after passing through the gas For a gas, the bright lines of the emission spectrum and the dark lines of the absorption spectrum often occur at the same wavelengths, as shown in Figure 28-6b and Figure 28-6c, respectively Thus, cool, gaseous elements absorb the same wavelengths that they emit when excited As you might expect, the composition of a gas can be determined from the wavelengths of the dark lines of the gas s absorption spectrum

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Antennas for radio direction finding (RDF)

Figure 28-6 This apparatus is used to produce the absorption spectrum of sodium (a) The emission spectrum of sodium consists of several distinct lines (b), whereas the absorption spectrum of sodium is nearly continuous (c)

Images were created by Dr Donald Mickey, University of Hawaii, Institute for Astronomy, from National Solar Observatory spectra data

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