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Tabulation of data for just the standard heats of reaction for all of the vast number of possible reactions is impractical Fortunately, the standard heat of any reaction can be calculated if the standard heats offormation of the compounds taking part in the reaction are known A formation reaction is defined as a reaction which forms a single compound from its constituent elements For example, the reaction C + ;o2+ 2Hz + CH30H is the formation reaction for methanol The reaction H 2 0 + SO3 --+ H2S04is not a formation reaction, because it forms sulfuric acid not from the elements but from other compounds Formation reactions are understood to result in the formation of 1 mol of the compound; the heat of formation is therefore based on 1 mol of the compound formed Heats of reaction at any temperature can be calculated from heat-capacity data if the value for one temperature is known; the tabulation of data can therefore be reduced to the compilation of standard heats of formation at a single temperature The usual choice for this temperature is 29815 K or 25 C The standard heat of formation of a compound at this temperature is represented by the symbol AH&, The degree symbol indicates that it is the standard value, subscript f shows that it is a heat of formation, and the 298 is the approximate absolute temperature in kelvins Tables of these values for common substances may be found in standard handbooks, but the most extensive compilations available are in specialized reference works9 An abridged list of values is given in Table C4 of App C



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example, see TRC Thermodynamic Tables-Hydrocarbons and TRC Thermodynamic Tables-Nonhydrocarbons, serial publications of the Thermodynamics Research Center, Texas A & M Univ System, College Station, Texas; "The NBS Tables of Chemical Thermodynamic Properties," J Physical and Chemical Reference Data, vol 11, supp 2, 1982 See also, T E Daubert et al, op cit Where data are unavailable, estimates based only on molecular structure may be found by the methods of L Constantinou and R Gani, Fluid Phase Equilibria, vol 103, pp 11-22, 1995





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As you can see, the central object tables contain a lot of information Keep this in mind as we go over exactly what happens when the Specification merge is run Now that we have covered the tables that are updated during the Specification merge, we will go over what the merge does Reading this chapter, you probably feel like you are drinking from a fire hose, but you will be prepared to troubleshoot an upgrade, including the Specification merge process When you kick off the Specification merge from the workbench, this process entails the tables the Specification merge uses to run, the Object Librarian merge, the Versions List merge, and the spec merge processes We will cover each of these topics in this section The Specification merge follows a logical process to move your objects from one release to the next, using some very specific tables These tables allow the merge to keep a log file and to keep track of what objects have been merged These tables are as follows: F98881 F988810 Specification Merge Logging File SpecMerge Tracking File

When chemical equations are combined by addition, the standard heats of reaction may also be added to give the standard heat of the resulting reaction This is possible because enthalpy is a property, and changes in it are independent of path In particular, formation equations and standard heats of formation may always be combined to produce any desired equation (not itself a formation equation) and its accompanying standard heat of reaction Equations written for this purpose often include an indication of the physical state of each reactant and product, ie, the letter g, 1, or s is placed in parentheses after the chemical formula to show whether it is a gas, a liquid, or a solid This might seem unnecessary since a pure chemical species at a particular temperature and 1 bar can usually exist only in one physical state However, fictitious states are often assumed for convenience Consider the reaction C02(g)+ H2(g)-+ CO(g) + H20(g)at 29815 K (25 C) This watergas-shift reaction is commonly encountered in the chemical industry, though it takes place only at temperatures well above 29815 K (25 C) However, the data used are for 29815 K (25"C), and the initial step in any calculation of heat effects concerned with this reaction is to evaluate the standard heat of reaction at 29815 K (25 C) The pertinent formation reactions and their heats of formation from Table C4 are:

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