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675 An insulated evacuated tank of 1 75-m3volume is attached to a line containing steam at 400 Wa and 51315 K (240 C)Steam flows into the tank until the pressure in the tank reaches 400 kPa Assuming no heat flow from the steam to the tank, prepare graphs showing the mass of steam in the tank and its temperature as a function of pressure in the tank 676 A 2-m3 tank initially contains a mixture of saturated-vapor steam and saturated-liquid water at 3000 kPa Of the total mass, 10% is vapor Saturated-liquid water is bled from the tank through a valve until the total mass in the tank is 40% of the initial total mass If during the process the temperature of the contents of the tank is kept constant, how much heat is transferred 677 A stream of water at 35815 K (85"C), flowing at the rate of 5 kg s-' is formed by mixing water at 29715 K (24 C) with saturated steam at 400 kPa Assuming adiabatic operation, at what rates are the steam and water fed to the mixer 678 In a desuperheater, liquid water at 3100 kPa and 32315 K (50 C) is sprayed into a stream of superheated steam at 3000 kPa and 64815 K (375 C) in an amount such that a single stream of saturated-vapor steam at 2900 kPa flows from the desuperheater at the rate of 15 kg s-I Assuming adiabatic operation, what is the mass flowrate of the water What is SG for the process What is the irreversible feature of the process 679 Superheated steam at 700 kPa and 55315 K (280 C) flowing at the rate of 50 kg s-' is mixed with liquid water at 31315 K (40 C) to produce steam at 700 kPa and 47315 K (200 C) Assuming adiabatic operation, at what rate is water supplied to the mixer What is Sc for the process What is the irreversible feature of the process 680 A stream of air at 12 bar and 900 K is mixed with another stream of air at 2 bar and 400 K with 25 times the mass flowrate If this process were accomplished reversibly and adiabatically, what would be the temperature and pressure of the resulting air stream Assume air to be an ideal gas for which C p = (7/2)R 681 Hot nitrogen gas at 67315 K (400 C) and atmospheric pressure flows into a waste-heat boiler at the rate of 1814 kg s-' , and transfers heat to water boiling at 1 atm The water feed to the boiler is saturated liquid at 1 atm, and it leaves the boiler as superheated steam at 1 atm and 42315 K (150 C) If the nitrogen is cooled to 43615 K (163 C) and if heat is lost to the surroundings at a rate of 140 kT for each kg of steam generated, what is the steam-generation rate If the surroundings are at 29415 K (21 C), what is SG for the process Assume nitrogen to be an ideal gas for which C p = (7/2)R 682 Hot nitrogen gas at 67315 K (400 C) and atmospheric pressure flows into a waste-heat boiler at the rate of 20 kg s-' , and transfers heat to water boiling at 10133 Wa The water feed to the boiler is saturated liquid at 10133 Wa, and it leaves the boiler as superheated steam at 10133 kPa and 42315 K (150 C)If the nitrogen is cooled to 44315 K (170 C) and if heat is lost to the surroundings at a rate of 80 kJ for each kilogram of steam generated, what is the steam-generation rate If the surroundings are at 29815 K (25"C), what is SG for the process Assume nitrogen to be an ideal gas for which C p = (7/2)R 683 Show that isobars and isochores have positive slopes in the single-phase regions of a T S diagram Suppose that C p = a b T , where a and b are positive constants Show that the curvature of an isobar is also positive For specified T and S, which is steeper: an isobar or an isochore Why Note that C p > C V.



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684 Starting with Eq (68), show that isotherms in the vapor region of a Mollier ( H S ) diagram have slopes and curvatures given by:

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Here, B is volume expansivity If the vapor is described by the two-term virial equation in P , Eq (337), what can be said about the signs of these derivatives Assume that, for normal temperatures, B is negative and d B / d T is positive

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685 The temperature dependence of the second virial coefficient B is shown for nitrogen on Fig 311 Qualitatively, the shape of B ( T ) is the same for all gases; quantitatively, the temperature for which B = 0 corresponds to a reduced temperature of about T, = 27 for many gases Use these observations to show by Eqs (653) through (655) that the residual properties G ~ H R , and S R are negative for most gases at modest pressures , and normal temperatures What can you say about the signs of v Rand c; 686 An equimolar mixture of methane and propane is discharged from a compressor at 5500 kPa and 36315 K (90 C) at the rate of 14 kg s-' If the velocity in the discharge line is not to exceed 30 m s-', what is the minimum diameter of the discharge line 687 Estimate vR,H ~ and sR for one of the following by appropriate generalized , correlations: ( a ) 1,3-Butadiene at 500 K and 20 bar (6) Carbon dioxide at 400 K and 200 bar ( c ) Carbon disulfide at 450 K and 60 bar ( d ) n-Decane at 600 K and 20 bar ( e ) Ethylbenzene at 620 K and 20 bar (f) Methane at 250 K and 90 bar (g) Oxygen at 150 K and 20 bar ( h ) n-Pentane at 500 K and 10 bar ( i ) Sulfur dioxide at 450 K and 35 bar (j) Tetrafluoroethane at 400 K and 15 bar 688 Estimate Z, H ~and sRfor one of the following equimolar mixtures by the LeelKesler , correlations: ( a ) Benzene/cyclohexane at 650 K and 60 bar (b) Carbon dioxidelcarbon monoxide at 300 K and 100 bar ( c ) Carbon dioxideln-octane at 600 K and 100 bar ( d ) Ethanelethylene at 350 K and 75 bar ( e ) Hydrogen sulfidelmethane at 400 K and 150 bar ( f ) Methanelnitrogen at 200 K and 75 bar ( g ) Methaneln-pentane at 450 K and 80 bar ( h ) Nitrogen/oxygen at 250 K and 100 bar.

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