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As you applied the combined gas law, you discovered how gases expand as their temperatures increase When heated, all forms of matter solids, liquids, and gases generally become less dense and expand to fill more space This property, known as thermal expansion, has many useful applications, such as circulating air in a room When the air near the floor of a room is warmed, gravity pulls the denser, colder air near the ceiling down, which pushes the warmer air upward This circulation of air within a room is called a convection current Figure 13-5 shows convection currents starting as the hot air above the flames rises You also can see convection currents in a pot of hot, but not boiling, water on a stove When the pot is heated from the bottom, the colder and denser water sinks to the bottom where it is warmed and then pushed up by the continuous flow of cooler water from the top This thermal expansion occurs in most liquids A good model for all liquids does not exist, but it is useful to think of a liquid as a finely ground solid Groups of two, three, or more particles move together as if they were tiny pieces of a solid When a liquid is heated, particle motion causes these groups to expand in the same way that particles in a solid are pushed apart The spaces between groups increase As a result, the whole liquid expands With an equal change in temperature, liquids expand considerably more than solids, but not as much as gases Why ice floats Because matter expands as it is heated, you might predict that ice would be more dense than water, and therefore, it should sink However, when water is heated from 0 C to 4 C, instead of expanding, it contracts as the forces between particles increase and the ice crystals collapse These forces between water molecules are strong, and the crystals that make up ice have a very open structure Even when ice melts, tiny crystals remain These remaining crystals are melting, and the volume of the water decreases until the temperature reaches 4 C However, once the temperature of water moves above 4 C, its volume increases because of greater molecular motion The practical result is that water is most dense at 4 C and ice floats This fact is very important to our lives and environment If ice sank, lakes would freeze from the bottom each winter and many would never melt completely in the summer.



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Figure 13-5 This image was made by a special technique that enables you to see different densities in the air Convection currents are set up as warmer, less dense air rises and cooler, denser air sinks

Figure 13-6 The colorful lighting effects in neon signs are caused by luminous plasmas formed in the glass tubing

10 void go() { 11 Account a1 = new Account(); 12 a1acctNum = new Long("1024"); 13 Account a2 = a1; 14 Account a3 = a2; 15 a3password = a1acctNumlongValue(); 16 a2password = 4455L; 17 } }





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If you heat a solid, it melts to form a liquid Further heating results in a gas What happens if you increase the temperature still further Collisions between the particles become violent enough to tear the electrons off the atoms, thereby producing positively charged ions The gaslike state of negatively charged electrons and positively charged ions is called plasma Plasma is considered to be another fluid state of matter The plasma state may seem to be uncommon; however, most of the matter in the universe is plasma Stars consist mostly of plasma at extremely high temperatures Much of the matter between stars and galaxies consists of energetic hydrogen that has no electrons This hydrogen is in the plasma state The primary difference between gas and plasma is that plasma can conduct electricity, whereas gas cannot Lightning bolts are in the plasma state Neon signs, such as the one shown in Figure 13-6, fluorescent bulbs, and sodium vapor lamps all contain glowing plasma

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10 Pressure and Force Suppose that you have two boxes One is 20 cm 20 cm 20 cm The other is 20 cm 20 cm 40 cm a How does the pressure of the air on the outside of the two boxes compare b How does the magnitude of the total force of the air on the two boxes compare 11 Meteorology A weather balloon used by meteorologists is made of a flexible bag that allows the gas inside to freely expand If a weather balloon containing 250 m3 of helium gas is released from sea level, what is the volume of gas when the balloon reaches a height of 2100 m, where the pressure is 082 105 Pa Assume that the temperature is unchanged 12 Gas Compression In a certain internal-combustion engine, 00021 m3 of air at atmospheric pressure and 303 K is rapidly compressed to a pressure of 201 105 Pa and a volume of 00003 m3 What is the final temperature of the compressed gas

13 Density and Temperature Starting at 0 C, how will the density of water change if it is heated to 4 C To 8 C 14 The Standard Molar Volume What is the volume of 1 mol of a gas at atmospheric pressure and a temperature of 273 K 15 The Air in a Refrigerator How many moles of air are in a refrigerator with a volume of 0635 m3 at a temperature of 200 C If the average molar mass of air is 29 g/mol, what is the mass of the air in the refrigerator 16 Critical Thinking Compared to the particles that make up carbon dioxide gas, the particles that make up helium gas are very small What can you conclude about the number of particles in a 20-L sample of carbon dioxide gas compared to the number of particles in a 20-L sample of helium gas if both samples are at the same temperature and pressure

When line 8 is reached, which are true (Choose all that apply) A a1acctNum == a3password B a1password == a2password C Three objects are eligible for garbage collection D Four objects are eligible for garbage collection E Six objects are eligible for garbage collection F Less than three objects are eligible for garbage collection G More than six objects are eligible for garbage collection 29 Given:

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