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elastomers (such as styrene-butadiene-styrene triblock copolymer). Semi uorinated alkyl substituents of the azo moieties may decrease the surface energy of azo BC lms. Moreover, it is possible for suf ciently long per uoroalkyl units to stabilize the surface so that azo photoisomerization does not change the surface properties (Paik et al., 2007). In addition, poly(2-methoxyethyl vinyl ether) [poly(MOVE)]base azo BC can supply the polymer surface with the thermally controlled water wettability because of the presence of the poly(MOVE) block (Yoshida, 2005).

Registry.publish("helloworld", new HelloWorld());

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At first the eight labels appear. Press Enter and they re gone. Press Enter again and they re back!

Azo BCs are one fascinating class of soft materials, showing a rich variety of microphase-separated nanostructures in lms because the strongly bonded azo segments and the non-azo blocks are thermodynamically incompatible. As shown in Fig. 12.1, the microphase-separated morphologies can be controlled to be spheres, cylinders, or lamellae, depending on the length, chemical nature, architecture, and number of repeated units in each block (e.g., Thomas and Lescanec, 1994). When the azo block shows LC properties, the inherent mesogenic ordering might act on the thermodynamic process of microphase separation by SMCM.

When your program needs to change a label, you simply reissue the slk_set() function for that label, along with the new text. Add a slk_refresh()and you re done (see Listing 12-4).

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1 2 3 4 5 6 7 8 9 10 11 12 13 14 #include <ncurses.h> #define LMAX 8 #define CENTER 1 int main(void) { char label_text[LMAX][8] = { Duck , Duck , Duck , Duck , Duck , Duck , Duck , Duck }; int label; slk_init(1); initscr();

The registry automatically generates a remotely-accessible WSDL for the Web Service. By default all public methods and interfaces of a remote object are accessible. Instead of publishing all methods, you can specify only that specific interfaces should be published. Even single methods can be published programmatically.

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The investigation of azo LCBCs can undoubtedly fertilize the detailed illustration of microphase separation, and completely novel nanostructures and phase behaviors are expected by the supramolecular self-assembly. Recently, a novel wormlike nanostructure composed of azo mesogens was observed in azo LCBC lms formed by PMMA155-b-PMA(11Az)25, as shown in Fig. 12.7. Although nanoscale wormlike morphologies have been obtained in micelles formed by BC solutions (Discher and Eisenberg, 2002), they have never been reported in bulk lms. Because of the difference in elastic modulus between amorphous PMMA and the azo LC phases, wormlike microphase domains were clearly observed in atomic force microscopic (AFM) images of the LCBC lms (Yu et al., 2007b). According to the molecular component of the azo BC, the wormlike domains with a width of 25 nm should be segregated by the azo blocks, leading to the disappearance of an LC texture after microphase separation because of the limited POM resolution. The novel wormlike nanostructures might be caused by the balance between microphase separation and LC self-assembly, which makes it different from the phase-segregated morphologies of BCs with weak molecular interactions (Yu et al., 2007b).

(continued)

Figure 12.7. Wormlike microphase-separated nanostructures obtained by supramolecular self-assembly in bulk lms of a well-de ned azo LCBC. Source: Reproduced with modi cations from Yu et al., 2007b.

The registry is also provided on the client side, where it is used to bind to a Web Services remote object. This is done by retrieving the WSDL INTERFACE DESCRIPTION of the Web Service. A CLIENT PROXY is then generated from this INTERFACE DESCRIPTION. Finally, the CLIENT PROXY is cast to one of the Web Services interfaces to allow for invocation of its methods. This can also be done programmatically:

Listing 12-4 (continued)

15 16 17 18 19 20 21 22 23 24 25 26 for(label=0;label<LMAX;label++) slk_set(label+1,label_text[label],CENTER); slk_refresh(); getch(); slk_set(7, Goose! ,CENTER); slk_refresh(); getch(); endwin(); return 0; }

Upon microphase separation, the azo moieties of relatively lower content aggregate together, which enables them to form easily an LC order in local areas, whereas a random copolymer of a similar azo content shows a statistical molecular structure, in which the azo moiety is homogeneously dispersed within the matrix of non-azo blocks No microphase separation can be observed since the azo block and the other blocks are completely miscible, resulting in an amorphous phase (Yu et al, 2008a) That is to say, the azo BC shows an LC phase more easily than an azo statically random copolymer with a similar low content of azo mesogens (Naka et al, 2009) As shown in Fig 128, although the random copolymer has a similar azo composition of B22 mol% to that of the well-de ned azo BC, it shows no LC phase.

String url = "http://localhost:8015/glue/helloworld.wsdl"; IHelloWorld hw = (IHelloWorld) Registry.bind(url, IHelloWorld.class);

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