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The curves shown on the P T diagram of Fig 31 represent phase boundaries for a pure substance A phase transition at constant temperature and pressure occurs whenever one of these curves is crossed, and as a result the molar or specific values of the extensive thermodynamic properties change abruptly Thus the molar or specific volume of a saturated liquid is very different from the molar or specific volume of saturated vapor at the same T and P This is true as well for internal energy, enthalpy, and entropy The exception is the molar or specific Gibbs energy, which for a pure species does not change during a phase transition such as melting, vaporization, or sublimation Consider a pure liquid in equilibrium with its vapor in a pistonlcylinder arrangement at temperature T and the corresponding vapor pressure P Sat When a differential amount of liquid is caused to evaporate at constant temperature and pressure, Eq (66) applied to the process reduces to d(nG) = 0 Since the number of moles n is constant, dG = 0, and this requires the molar (or specific) Gibbs energy of the vapor to be identical with that of the liquid More generally, for two phases a, and B of a pure species coexisting at equilibrium, G" = GB (666) where G a and GB are the molar or specific Gibbs energies of the individual phases



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Let s use a quick example Company X decides to hire one of the EnterpriseOne application developers This developer s salary is $75,000 per year with the opportunity of another $75,000 in bonus Company X agrees to hire this employee at $150,000 per year with a three-year minimum contract protecting the consultant and their investment in them Company X approaches the consulting firm s management about the arrangement and they decide to hold Company X to its contractual obligations instead of releasing them (Not holding the company would of course be a great gesture toward ensuring good relations; however, a significant percentage of the time, the firm will charge the client anyway) Company X would owe the consulting firm $37,500 for hiring the developer The reason is that the developer s salary was $75,000 The bonus potential (though certainly a factor in the salary that Company X had to pay the consultant) doesn t factor into the equation The only way that Company X would get by without paying anything is if they decided not to hire the developer after all and this is exactly what the consulting firms are hoping will occur Of course, the contract the consultant cleverly had signed prior to Company X approaching the consulting firm protects the consultant in this scenario NOTE This practice is standard across the consulting industry After all, the real product that consulting firms sell is their consultants knowledge

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The Clapeyron equation, first introduced in Sec 42, follows from this equality If the temperature of a two-phase system is changed, then the pressure must also change in accord with the relation between vapor pressure and temperature if the two phases continue to coexist in equilibrium Since Eq (666) applies throughout this change,

Substituting expressions for d G and dGB as given by Eq (610) yields: V f f d P S a t S f f d T = v B d p s a t- S B ~ T which upon rearrangement becomes:

The actual licensing of the EnterpriseOne product is relatively lax compared with strict IS standards There are multiple methods of cheating the software itself and getting more people on the system than you should, as we ve pointed out earlier However, you should also be aware of Oracle s right to audit your computer system If they find that you are in violation of the software agreement signed earlier, it could cost you licensing fees, penalties, or a loss of the software itself Our best advice to you is to follow your licensing agreement to the letter Can you cheat the system Sure But if you get caught, it could include fines, your company firing you, and even jail time Is saving your organization some money up front worth this to you

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