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the isotopic shifts These are needed to limit the number of solutions in a force constant calculation (Sec 42235) To the same end, a number of isotopomers of 0x0-anions were investigated by 1R In order to obtain sharp bands, the following species are sometimes incorporated in high dilution in solid matrices, such as alkali halides: ClO,, SO: , SeO: , CrOi- and WO (Becher et al, 1973 and 1976) Isotopic shifts between "Mo and 'O0Mo were measured in order to obtain a force field of the MOO: anion (Miiller et al, 1974) For more information about the metal isotope effect on molecular vibrations, the review of Mohan et al (1975) is recommended.



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Like any other organization, government entities want to move into the digital era, becoming click-and-mortar organizations. However, the transformation from traditional delivery of government services to full implementation of online government services may be a lengthy process. The business consulting rm Deloitte and Touche conducted a study (see Wong, 2000) that identi ed six stages in the transformation to e-government: Stage 1: Information publishing/dissemination. Stage 2: Of cial two-way transactions, with one department at a time.

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Since the vibrations of molecules are anharmonic, it is important to remember that the frequencies of the different isotopomers only afford the same force constant if the amplitudes are assumed to be infinitesimally small The distortion which is caused by the different anharmonicity of the vibrations in isotopomeric molecules is often small compared to the accuracy of the measurement This is especially true for small isotopic shifts (about 1-5 cm I ) As a result of the development of new, improved techniques (eg, FT-spectrometers, matrix isolation), frequencies can sometimes be determined with an accuracy of more than 01 cm I If isotopic shifts can be measured so accurately, they have to be corrected for anharmonicity, even if the isotopic shift is in the range of a few cm-'.

where the intersection area is normalized to [ 0, 1] and 0 is a coef cient regulating its behavior ( = 0 gives no penalty). This term is computed for all overlapping target pairs under the ensemble hypothesis s, thus giving (s) =

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The sequential decoding with long memory convolutional codes is a powerful coding technique, but it is not used in satellite communication systems, so will not be presented. b) Binary and non-binary block codes associated with algebraic decoding. In this category, the most successful application is the Reed-Solomon code. The block coded modulations are another generalization of this second category, when they are jointly optimized with modulation schemes. The block codes can be divided into the following classes: BCH codes decodable by the algebraic decoding, including the Reed-Solomon codes as a non-binary subclass in BCH codes; Cyclic codes used for error detection; Simple codes such as the Hamming codes, Reed-Muller codes and certain particularly good ones: Golay, QR (Quadratic Residual), etc.

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Since the required exact anharmonicity constants are generally unkown, an approximation has been suggested (Becher, 1968) which proved to be practicable, except for H/D substitution This method involves using the anharmonicity constant x, of a simpler compound which contains the same bond as the investigated compound If no other data are available, x, values of the diatomic species (Huber and Herzberg, 1979) have to be used The corrected isotopic shift AY,,~,-,is calculated using the following expression:.

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3.3.1.2 Delta modulation (DM)

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