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This is the standard screen. To see the window bob, press the Enter key: Welcome back to the standard screen (kinda). To see the whole window bob, press Enter.

1.2.6.1. Photoswitches. As already pointed out, the azo isomerization can be used to photoswitch a wide variety of other properties (at numerous size scales). In addition to the optical changes already described, it is worth noting that the transient change in material refractive index (owing to the different n of cis and trans) can itself act as a photoswitch (Barley et al., 1991). The azo photochromism

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has even been suggested as a possible optical neural network element (Sumaru et al, 1999) Binding and transport properties can also be photoswitched (Weh et al, 1998; Anzai and Osa, 1994) In some systems the redox potential and ionic conductivity can be switched with light (Willner and Willner, 1997) Crown ethers (Zawisza et al, 1999; Tokuhisa et al, 1994) and calixarenes (Reynier et al, 1998) functionalized with azobenzene can be used as reversible ion-binding systems Thus, ion transport can be photoregulated In other cases, the transport properties can be photocontrolled not via binding but on the basis of changes in pore sizes (Sata et al, 2000; Abraham and Purushothaman, 1998; Kano et al, 1980) In a particularly elegant example, the size of nanochannels could be modi ed by irradiating azo ligands that decorate the channel walls (Liu et al, 2004).





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TRUE is a Boolean value used in NCurses for setting options, as a value returned by specific functions, or for comparisons.

TRUE can be used in one of the following ways:

Azoderivatized gramicidin ion channels represent a unique case where ion transport can be photocontrolled by the optical manipulation of a biomolecule (Lien et al, 1996) In addition to obvious applications in controlled transport, this offers the possibility of studying cells by controlling the timing of ion exchange processes Photoinduced catalysis is also possible, for instance, using molecules where only the cis form is catalytically active (Wuerthner and Rebek, 1995) Extension of the molecular imprinting technique to azo polymers allows for photoswitching of binding activity with respect to the imprinted molecule (Minoura et al, 2004) 1262 Photoprobes The properties of an azo chromophore (spectrum, isomerization kinetics, etc) depend strongly on the local environment This enables the possibility of using the chromophore as a molecular sensing element: a photoprobe.

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For instance, it has been found that many azo properties depend on local H+ concentration, to the extent that the azo can in fact be used as a pH meter (Uznanski and Pecherz, 2002; Mermut and Barrett, 2001) As mentioned earlier, the isomerization kinetics can also be used as a probe of free volume (Naito et al, 1993; Lamarre and Sung, 1983), local aggregation (Norman and Barrett, 2002), or phase transitions The azo molecule is small and exhibits clean photochemistry, which makes it more versatile and robust than many other photoprobes The rate of isomerization is also remarkably insensitive to temperature (Yamamoto, 1986), yet sensitive to local solvent conditions (Li et al, 2006; Norman and Barrett, 2002) This is an area of research that deserves considerably more attention In a more sophisticated example, azo chromophores were used to monitor protein folding (Bredenbeck et al.

In this statement, the value returned by the function can be either TRUE or FALSE and is stored in the var variable. var is declared as a bool value.

Note that when accessed asynchronously, a remote object is very similar to an Active Object in [SSRB00]. An Active Object decouples method invocation from method execution. The same holds true for remote objects that use any of patterns presented here for asynchronous communication. However, when remote objects are invoked synchronously, the invocation and execution of a method is not decoupled, even though they run in separate threads of control. Active Objects typically create Future [Lea99] objects that clients use to retrieve the result from the method execution. The implementation of such Future objects follows the same concepts that are presented in RESULT CALLBACK and POLL OBJECT.

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