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E E E In the SYNC WITH SERVER pattern, as in FIRE AND FORGET, no return value or out parameters of the remote operation are sent back to the client. The reply sent by the server application is only to inform the REQUESTOR about successful reception of the request. If the distributed object middleware supports SYNC WITH SERVER operations, the SERVER REQUEST HANDLER can send an acknowledgment message immediately after reception of the invocation. Alternatively, if only synchronous invocations are supported, SYNC WITH SERVER can be emulated at the application level inside the operations of the remote object. The operation of the remote object spawns a new thread that performs the actual invocation, while the INVOKER thread that initially invoked the operation returns immediately and returns an acknowledgement back to the client. Compared with FIRE AND FORGET, SYNC WITH SERVER operations ensure successful transmission, and thus make remote invocations more reliable. However, SYNC WITH SERVER incurs additional latency the client has to wait until the reply from the server application arrives. Note that the REQUESTOR can inform the client of system errors, such as failed transmission of the invocation. However, it cannot inform clients about application errors during the remote invocation in the remote object, because this happens asynchronously after the acknowledgement has already been sent to the server.



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Figure 7.11. Light-responsive and reversible inversion of emulsion (dodecane/ water+NaNO3). The conductivity measurements indicate the type of continuous phase (conducting water vs. insulating oil) in samples maintained under gentle agitation (stirring bar). The emulsi er contains an azobenzene-modi ed polyacrylate (n = 5, x = 3% in Fig. 7.1) and a temperature-responsive surfactant (C12E4) that in absence of polymer would stabilize inverse emulsion above 241C. (a) Temperature sweep of the same sample exposed to UV or blue light. (b) Switches of the wavelength of exposure between UV and blue lights at xed temperature (251C) at times pointed by arrows.

subpad()

25.09.2004 21:11

The subpad() function creates and defines a rectangle on a pad as a subpad, much the same as subwin() creates a subwindow.





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It is interesting to study whether the azobenzene molecular conformational rearrangements can result in changes to bulk phenomena, or even to macroscopic motion. The rst consideration is whether the material expands to an appreciable extent. In monolayers, it is well established that the larger molecular size of the cis isomer leads to a corresponding lateral expansion (Higuchi et al., 1995b), which can modify other bulk properties. For instance, this allows photomodulation of a monolayer s water contact angle (Siewierski et al., 1996) or surface potential (Stiller et al., 1999). Using uorinated azo polymer, good photocontrol (Feng et al., 2001) and photopatterning (Moller et al., 1998) of wettability has been demonstrated. A monolayer of azo-modi ed calixarene, when irradiated with a light gradient, produced a gradient in surface energy suf cient to move a macroscopic oil droplet (Ichimura et al., 2000), suggesting possible applications in micro uidics. Modest photoinduced contact angle changes for thin polymer lms have also been reported (Sarkar et al., 2001). Recently an azobenzene copolymer assembled into polyelectrolyte multilayer showed a modest 21 change in contact angle with UV light irradiation. However, when the same copolymer was assembled onto a patterned substrate, the change in contact angle upon irradiation was enhanced to 701 (Jiang et al., 2005). It is well established that

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WINDOW *subpad(WINDOW *orig, int nlines, int ncols,int begin_y, int begin_x);

surface roughness plays a role in contact angle and many systems can be optimized to give rise to a large change in surface properties In layered inorganic systems with intercalated azobenzenes, reversible photochanges in the basal spacing (on the order of 4%) can be achieved (Fujita et al, 1998, 2001) In polymer lms, there is some evidence that the lm thickness increases, as measured by ellipsometry (Shi et al, 1991b) (the refractive index certainly changes [Ivanov et al, 1995], but this is not an unambiguous demonstration of expansion contraction) Experiments that show that external applied pressure tends to hinder photoisomerization (Kleideiter et al, 2000) are related Photocontraction for semicrystalline main-chain azos has been measured (Eisenbach, 1980b; Agolini and Gay, 1970) This photomechanical response presumably occurs because of the shortening of the polymer chains upon trans-cis conversion.

orig is a WINDOW variable, a pointer, representing the parent pad. nlines and ncols are int values that set the subpad s size in rows and columns. Values for nlines and ncols cannot be larger than the parent pad. begin_y and begin_x are int values that set the subpad s position relative to the parent pad. The value 0,0 is the parent pad s upper-left corner.

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