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Bulk polymerization of vinyl chloride and solution polymerization of crylonitrile in water are examples of precipitation polymerization Precipitation polymerizations are often referred to as powder or granular polymerizations because of the forms in which the nal polymer products are obtained The initiators used in precipitation polymerization are soluble in the initial reaction medium Polymerization proceeds after precipitation by absorption of monomer and initiator (and/or initiating radicals) into the polymer particles Suspension polymerization (also referred to as bead or pearl polymerization) is carried out by suspending the monomer (discontinuous phase) as droplets (50 500 mm in diameter) in water (continuous phase) Styrene, acrylic and methacrylic esters, vinyl chloride, vinyl acetate, and tetra uoroethylene are polymerized by the suspension method The water: monomer weight ratio varies from 1 : 1 to 4 : 1 in most polymerizations. 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