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One important prerequisite to the application of this reaction in hydrocarbon synthesis is the selective monochlorination of methane Usual radical chlorination of methane is not selective, and high CH4 : Cl 2 ratios are needed to minimize formation of higher chlorinated methanes (see Section 1025) In contrast with radical halogenation, electrophilic halogenation of methane was shown to be a highly selective process 412 A range of superacid catalysts such as NbOFr AI 20 3, ZrOF2-AI 20 3, SbFsgraphite, and TaFs-Nafion-H effect the chlorination and bromination of methane 411 ,413 ZrOF2-AI 20 3 gives the best results in chlorination (96% selectivity at 34% conversion), and SbOFr Al 20 3 is the best for bromination (99% selectivity at 20% conversion) Supported platinum and palladium catalysts are also very effective with selectivities also exceeding 90% (99% selectivity at 36% conversion over 0.





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The avour of beer can be split into three separate components: taste, smell (aroma) and texture (mouthfeel). There are only four proper tastes: sweet, sour, salt and bitter. They are detected on the tongue. A related sense is the tingle associated with high levels of carbonation in a drink: this is due to the triggering of the trigeminal nerve by carbon dioxide. This nerve responds to mild irritants, such as carbonation

5% platinum on alumina at 250 C, with a feed composition of CH 4 : Cl 2 = 3: 1)411 Solid acids and zeolites have also been found to be very selective in monochlorination 476,477 Hydrogen chloride formed during the chlorination of methane must be oxidized to chlorine, either in the oxychlorination of methane478 or in a separate Deacontype operation to allow the process to become economical This is still difficult to achieve Existing data also show that formation of higher chlorinated methane derivatives is often also a difficulty of the reaction 479-481 These difficulties can be minimized by using bromine in the catalytic oxidative conversion process Hydrocarbon formation from methyl chloride can be catalyzed by ZSM_5 482,483 or bifunctional acid-base catalysts such as W0 3 on alumina 42o ,447 The reaction on ZSM-5 gives a product distribution (431% aliphatics and 57.

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