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Seki and coworkers (2007) developed a new type of photoresponsive polymer gel by introducing an azobenzene moiety on the mobile cyclodextrin part as the sliding cross-linking unit. The synthesis scheme of the gel is shown in Fig. 3.3. The polyrotaxane (PR) was composed of a noncovalent complex between poly(ethylene oxide) and a-cyclodextrin (a-CD, lling ratio: 28% of full complexation) capped with an adamantanamine unit at each end. Onto the sliding ring of CD, three types of azobenzene derivatives (6Az10-, 6Az(EO)3-, and CNAz(EO)3-) were linked by esteri cation. Gelation reactions, namely, formation of gure-of-eight sliding cross-linkages of the azobenzene-linked PR, were performed with 1,1carbonyl diimidazole in dimethyl-sulfoxide (DMSO). Figure 3.4 indicates volume changes of the gels in DMSO upon irradiation of alternate UV and visible light. For all three systems, irradiation of UV light induced expansion of the gels, and visible light the reverse. The change in D/D0 for 6Az10-PR gel reached 25%, which corresponds to a volume change of 80% 100%. It is inferred that such an effective molecule-to-material transformation can be ascribed to the dynamic nature of the cross-linkers (Sakai et al., 2007).



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This is one of the rare text color function in NCurses that uses the plural colors. The other two are assume_default_colors() and use_default_colors().

for the remote objects can typically be serialized into a string and exchanged between server application and client manually via configuration files, or even e-mail. But doing this on every client restart or change of configuration is tedious.

r = has_colors();

CH3(CH2)5

After this statement, the value of r will equal TRUE if the terminal can produce color text, FALSE otherwise.

6Az(EO)3

if(has_colors)





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Reusing references obtained during previous runs of the client program has to be done with care, because the reference to the remote object might be transient, and therefore might have become invalid as a consequence of a server application restart, or the relocation of the service on another remote object hosted by a different server application. Even in the case of non-opaque ABSOLUTE OBJECT REFERENCES references constructed by the client the client would have to know the endpoint information, INVOKER ID and OBJECT ID. Clients typically do not know this information, because this would compromise the goal of location transparency, one of the fundamental concepts of distributed object middleware. Another way to obtain a reference for a specific remote object is to invoke an operation of some other remote object that returns the desired reference. However, where does the client get the reference to the other remote object from Therefore: Implement a lookup service as part of the distributed object middleware. Let server applications register references to remote objects and associate them with properties. Clients then use the lookup service to query for the ABSOLUTE OBJECT REFERENCES of remote

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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 #include <ncurses.h> int main(void) { bool tf; initscr(); tf = has_colors(); if( tf == TRUE) addstr( This terminal can do colors.\n ); else addstr( This terminal cannot do colors.\n ); refresh(); getch(); endwin(); return 0; }

CNAz(EO)3

Sample output:

24.09.2004 20:27

has_ic()

Figure 3.3. Synthesis scheme of azobenzene-containing slide-ring gels. Source: Sakai et al., 2007.

The has_ic() function determines whether the terminal has the ability to insert and delete characters.

bool has_ic(void);

Identification Patterns objects based on these properties. The most common case is to use unique names for each reference of a remote object.

Polymer gels have attracted special attention for possible applications in the biomedical eld; however, low elastic modulus and low yield strength of the gels provide important limitations for their performance. Polymers are one of the most superior materials in view of their high processability, ability to form self-standing lms with thicknesses from nanometers to centimeters, lightweight, exibility in molecular design, and precisely controllable synthesis. Many kinds of polymers have been put to practical use in daily life and industry. From this point of view, polymer actuators capable of responding and deforming in response to external stimuli are most desirable for practical applications. Various chemical and physical stimuli have been applied to induce deformation of polymer actuators, for example, temperature changes (Liu et al., 2002), electric elds (Fukushima et al., 2005; Otero and Cortes, 2003), and solvent composition (Gao et al., 2003).

A Boolean value is returned: TRUE if the terminal has insert and delete character capabilities, FALSE if not.

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