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Self-assembly of amphiphilic polymers generally refers to the micellar aggregation of the amphiphilic block or graft copolymers in the selective solvents It is well known that surfactant molecules can well organize to form micelles in solutions when the concentration is above the critical micelle concentration (CMC) (Shaw, 1992; Hiemenz, 1986) The micellization can be attributed to factors such as hydrophobic effect and the intermolecular attraction between the hydrocarbon segments Amphiphilic block and graft copolymers can be considered as polymeric counterparts of the low-molecular-weight surfactants (Halperin, 1987; Cantor, 1981) Various micellar aggregates have been prepared from block or graft copolymers through self-assembly of the polymeric chains in suitable selective solvents (see, eg, Kikuchi and Nose, 1996; Kabanov et al, 1995; Zhang and Eisenberg, 1995; Balsara et al, 1991; Wilhelm et al, 1991).



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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 #include <ncurses.h> #define UNI 4.5 int main(void) { int pieces = 0; initscr(); addstr( SUSHI BAR MENU\n\n ); printw( We have Uni today for $%.2f.\n ,UNI); addstr( How many pieces would you like ); refresh(); scanw( %d ,&pieces); printw( You want %d pieces \n ,pieces); printw( That will be $%.2f!\n ,UNI*pieces); refresh(); getch(); endwin(); return 0; }

invoke(i,c)

Sample output:





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Amphiphilic block copolymers can form uniform micellar spheres with a hydrophobic core and a hydrophilic corona in aqueous media or form reverse micelles in organic solvents Depending on the relative size of the core and corona, the block copolymers can form starlike micelles and crew-cut micelles (Shen et al, 1997) A general method has been developed by Eisenberg and coworkers to prepare micellar aggregates from amphiphilic block copolymers (Zhang et al, 1997; Zhang and Eisenberg, 1995; Gao and Eisenberg, 1993) In the process, deionized water is slowly added into a diluted solution of the polymers in an organic solvent such as tetrahydrofuran (THF) When the water content reaches a critical value, the polymeric chains start to aggregate The water content at this point is de ned as the critical water content (CWC).

SUSHI BAR MENU We have Uni today for $4.50. How many pieces would you like 3 You want 3 pieces That will be $13.50!

2, getstr(), printw()

getInterceptors()

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When more water is added into the suspension, the structures of the formed aggregates will be frozen and stable suspensions of the micellar aggregates can be obtained Depending on the compositions of the block copolymers, the micellelike aggregates can be spheres, rods, lamellae, and vesicles (Zhang and Eisenberg, 1995) Generally, uniform micelles can only be obtained from block copolymers with narrow distribution in both the molecular weight and block length These wellde ned copolymers are prepared by some rather sophisticated polymerization methods, such as the anionic living polymerization and ATRP The effect of dispersity of the block copolymer, such as distribution of segment length and molecular weight, has been studied by several groups (Terreau et al, 2004; Linse, 1994; Hadziioannou and Skoulios, 1982).

scr_dump()

int scr_dump(const char *filename);

Results indicate that the polydispersity can signi cantly in uence the parameters such as CMC and lead to the formation of different morphologies in the same system It can be imagined that for polymers with wide dispersion in molecular weight and solubility, adding precipitant slowly is more likely to cause the polymer to precipitate according to the solubility This fractionation process has been widely used to prepare polymers with narrow molecular weight distribution However, recent studies in this laboratory show.

beforeInvocation(i,c)

filename is the name of a file under which the standard screen data will be saved. It is not a FILE pointer.

trans-azo (small dipole moment)

The scr_restore() function is the companion to scr_dump(), restoring the image saved to disk and back to the virtual screen. The file format used by scr_dump() is the same as for putwin(). In fact, the getwin() function can be used to read in the file created by scr_dump(). Remember that the scr_dump() function s argument is a filename, not a FILE pointer!

get("securityToken") opt [token is ok]

scr_dump(screen);

cis-azo (large dipole moment)

Here, the scr_dump() function saves the current screen to disk using the file specified by the screen variable.

scr_dump( test.win );

Figure 6.1. Schematic illustration of light-controllable micelles and vesicles formed by azobenzene-containing block copolymers displaying the trans cis photoisomerization. See color insert.

anOperation()

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 #include <ncurses.h> #include <stdlib.h> #include <time.h> #define FILENAME windump int main(void) { char word[7]; int x,w,r; srandom((unsigned)time(NULL)); word[7] = \0 ; initscr(); /* seed randomizer */

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