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Several mechanisms have been described to account for the microscopic origin of the driving force in azobenzene optical patterning. Arguments have appealed to thermal gradients, diffusion considerations, isomerization-induced pressure gradients, and interactions between azo dipoles and the electric eld of the incident light. Considering the large body of experimental observations, it is perhaps surprising that the issue of mechanism has not yet been settled. At present, no mechanism appears to provide an entirely complete and satisfactory explanation consistent with all known observations. However, viscoelastic modeling of the process has been quite successful, correctly reproducing nearly all experimentally observed surface patterns, without directly describing the microscopic nature of the driving force. Fluid mechanics models provided suitable agreement with observations (Barrett et al., 1998) and were later extended to take into account a depth dependence and a velocity distribution in the lm (Fukuda et al., 2000b; Sumaru et al., 1999), which reproduces the thickness dependence of SRG



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inscription. A further elaboration took into account induced anisotropy in the lm and associated anisotropic polymer lm deformation (expansion or contraction in the electric eld direction) (Bublitz et al., 2001). The assumption of an anisotropic deformation is very much consistent with experimental observations (Bublitz et al., 2000). Such an analysis, remarkably, was able to reproduce most of the polarization dependence, predict phase-inverted behavior at high power, and even demonstrated double-period (interdigitated) gratings. A nonlinear stressrelaxation analysis could account for the nonlinear response during intermittent (pulselike) exposure (Saphiannikova et al., 2004b). Finite-element linear viscoelastic modeling enabled the inclusion of nite compressibility (Saphiannikova et al., 2004a). This allowed the nonlinear intermittent-exposure results, and, critically, the formation of DGs, to be correctly predicted. This analysis also demonstrated, as expected, that surface tension acts as a restoring force that limits grating amplitude (which explains the eventual saturation). Finally, the kinetics of grating formation (and erasure) have been captured in a lattice Monte Carlo simulation that takes into account isomerization kinetics and angular redistribution of chromophores (Mitus et al., 2004; Pawlik et al., 2004, 2003). Thus, the nonlinear viscoelastic ow and deformation (compression and expansion) of polymer material appear to be well understood. What remains to be fully elucidated is the origin of the force inside the material. More speci cally, the connection between the azobenzene isomerization and the apparent force must be explained.

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