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Figure 3.27. (a) Photographs of the ferroelectric LCE lm that exhibits bending and unbending behavior upon alternative irradiation with UV and visible light at room temperature: the lm bent toward the actinic light source along the alignment direction of mesogens in response to irradiation at l = 366 nm, and being attened again by irradiation with visible light at lW540 nm. (b) Change of the load on the ferroelectric LCE lm when exposed to UV light at l = 366 nm with different intensities at 501C. The cross-section area of the lm is 5 mm 20 mm. An external force of 20 mN was loaded initially on the lm to keep the length of the lm unchanged. Source: Yu et al., 2007.



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24.09.2004 20:59

The slings and arrows of outrageous fortune, Or to take arms against a sea of troubles, And by opposing end them

Whether tis nobler in the mind to suffer The slings and arrows of outrageous fortune, Or to take arms against a sea of troubles, And by opposing end them

Figure 1.7. An azobenzene dendrimer containing three azo moieties. Each chromophore has two isomerization states (trans and cis), leading to four distinct photoisomers for the dendrimer molecule. All four isomers have different physical properties.

To be, or not to be: that is the question: Whether tis nobler in the mind to suffer The slings and arrows of outrageous fortune, Or to take arms against a sea of troubles, And by opposing end them





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Clients consume server application resources, for example by using CLIENT-DEPENDENT INSTANCES E E E Remote objects and their servants that are no longer needed should be released in time to free unused system resources However, the LIFECYCLE MANAGER cannot determine when a particular remote object is no longer used so that it can release it safely In most scenarios, neither the LIFECYCLE MANAGER nor the remote object itself have knowledge of the clients, and so do not know whether they intend to access the remote objects in the future Consider a stateful remote object that is accessed by a single client, such as a CLIENT-DEPENDENT INSTANCE The easiest way for a LIFECYCLE MANAGER to know that a remote object is no longer needed is when the client invokes a destroy operation on the remote object.

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Rubner, 2000) (in the case of weak polyelectrolytes) of the assembly solution, the polyelectrolyte chain conformation is modi ed, and hence the resulting lm architecture is tuned. For instance, one can control thickness (Losche et al., 1998; Dubas and Schlenoff, 1999), permeability (Rmaile and Schlenoff, 2003), morphology (Antipov et al., 2003; McAloney et al., 2003; Mendelsohn et al., 2000), and density (Dragan et al., 2003). Recently the technique has been modi ed to assemble the alternate layers using a spin-coater, which reduces the assembly times and adsorption solution volumes considerably (Chiarelli et al., 2001; Cho et al., 2001; Lee et al., 2003, 2001). As a lm preparation technique, this method has numerous advantages. The adsorption of the polymers is quasithermodynamic, with the chains adsorbing into a local minimum, which makes the lms stable against many defects (dewetting, pinhole formation, etc.). Importantly, the technique is not limited to at surfaces: any geometry that can be immersed in solution (or have solution owed through)

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is suitable Colloids have been ef ciently coated with PEMs (Caruso, 2001; Sukhorukov et al, 1998b), and by dissolving the core one can also form hollow PEM microcapsules (Sukhorukov et al, 1998a) Multilayers can be formed on nearly any material (glass, quartz, silicon, most metals, etc) and are robust against thermal and solvent treatment (Mermut and Barrett, 2001) One of the main interests in PEMs is due to their inherent biocompatibility (Richert et al, 2002): multilayers have been formed on enzyme microcrystals (Jin et al, 2001), used to encapsulate living cells (Diaspro et al, 2002) and coat arterial walls (Thierry et al, 2003) Perhaps the most useful feature of the multilayering technique is its ability to incorporate secondary functional groups into the thin lm structure.

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