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This statement directs NCurses to turn on the echo of text to the screen for input during the getch(), getstr() and related functions.

[HV99] [HW03]

noecho();



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(Fig. 2.8). Side-chain polymers are more typical, and commercially available polymer PAZO (Aldrich) was already used for LbL assembly in 1997 (Lvov et al., 1997). Both PAZO and PS-119 (Fig. 2.8) could be considered as strong polyelectrolytes being in salt form. It is important that charged group be connected to azobenzene moiety, and therefore one can expect the ionic interactions responsible for the formation of LbL structure to restrict azobenzene motion. Birefringence value of 0.09 for the 200-nm lm (dos Santos et al., 2006) was achieved for structures of PS-119 with cationic dendrimers. Interestingly, for higher dendrimer generation (with higher charge density) stronger absorption of PS-119 has been observed. That fact led to the lower values of birefringence, which is related to restriction of chromophore molecular motion. For PS-119/PAH architecture

This statement disables the display of text to the screen for the getch(), getstr(), and related text input functions.





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1 #include <ncurses.h> 2 #include <ctype.h> 3 4 int main(void) 5 { 6 int ch; 7 87 initscr(); 9 10 addstr( Normally echo is on. Type your name and press ; Enter:\n ); 11 refresh(); 12 while( getch() != \n ) 13 ; 14 15 mvaddstr(2,0, Now echo is off. Type your name and press ; Enter:\n ); 16 refresh(); 17 noecho(); 18 while( getch() != \n ) 19 ; 20 21 mvaddstr(4,0, Echo is still off, but input is being ; displayed\n );

Figure 2.8. Chemical formula of azobenzene-containing polyelectrolytes used for the preparation of LbL multilayers and supramolecular complexes.

[Ibm04a]

22 addstr( and manipulated manually. Type your name and press ; Enter:\n ); 23 do 24 { 25 ch = getch(); 26 addch(toupper(ch)); 27 refresh(); 28 } while( ch != \n ); 29 30 addstr( Press Enter to quit: ); 31 refresh(); 32 getch(); 33 34 endwin(); 35 return 0; 36 }

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(Zucolotto et al., 2004b), the structure and charge density of cationic polyelectrolyte PAH can be governed by pH during LbL deposition, and it changes the LbL lms properties. By increasing the pH from acidic to basic, it was possible to increase the bilayer thickness by the factor of 2.4 because of the loose conformation of PAH in the LbL structure. The authors compared the lms with similar amount of azobenzene (the same optical absorption) prepared at different pH and came to the conclusion that an increase in the pH led to a slowing of kinetics of the induction of photoorientation by the factor of 4. For another similar polyelectrolyte PAZO (Fig. 2.8), the data on photoinduced orientation in LbL structures are not available. In contrast to LbL structures, the results on ionic complex of PAZO with PEI (Stumpe et al., 2006a) showed that dichroism was lower in this case compared with the neat PAZO lms (Stumpe et al., 2006b; Goldenberg et al., 2005), approximately proportional to a decrease in azobenzene loading. It seems that there is no restriction of azobenzene motion by ionic interactions with oppositely charged polyelectrolyte in this complex. This demonstrates that the layered structure of the LbL lms should be responsible for this restriction. Two other azobenzene-containing polyelectrolytes (Fig. 2.8) are copolymers. The important difference is that ionizable group (COOH) is attached not to the azobenzene but to another unit on the polymer chain. Therefore, one could expect

Sample output:

24.09.2004 20:26

Now echo is off. Type your name and press Enter:

that ionic interactions, necessary for the LbL organization, will have lower impact on the properties of azobenzene moiety However, some of these copolymers (PBANT-AC, PBACT-AC, PAA-AZ) exhibited only low dichotic ratio (up to 13) (Wang et al, 2004a,b) Other LbL structures with PAA-AN, MA-co-DR13 showed birefringence value up to 0068 (Zucolotto et al, 2002; Lee et al, 2000) It should be noted that spin-coated lms (Lee et al, 2000) showed the same results, and it means that there is no advantage in tedious LbL assembly in this case Also, the authors (Zucolotto et al, 2002) mentioned much longer time necessary to induce maximum value of orientation in LbL systems, and this was attributed to the in uence of ionic and H-bonding interactions In addition, the drier was the LbL lm, the more sluggish was the kinetics of induction of photoorientation.

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