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The P-T diagram of Fig 105 is typical for mixtures of nonpolar substances such as hydrocarbons A P-T diagram for a very different kind of system, methanol(l)/benzene(2), is shown in Fig 107 The nature of the curves in this figure suggests how difficult it can be to predict phase behavior for species so dissimilar as methanol and benzene Although VLE in the critical region is of considerable importance in the petroleum and natural-gas industries, most chemical processing is accomplished at much lower pressures Figures 108 and 109 display common types of P-x-y and t-x-y behavior at conditions well removed from the critical region Figure 108(a) shows data for tetrahydrofuran(l)/carbon tetrachloride(2) at 30315 K (30 C) Here, the P-xl or bubblepoint curve on a P-xl-yl diagram lies below the linear P-xl relation characteristic of Raoult's-law behavior, as described in the following section When such negative departures from linearity become sufficiently large relative to the difference between the two pure-species vapor pressures, the P-x curve exhibits a minimum, as illustrated in Fig 108(b) for the chloroform(l)/tetrahydrofuran(2)system at 30315 K (30 C) This figure shows that the P-yl curve also has a minimum at the same point Thus at this point where xl = yl the dewpoint and bubblepoint curves are tangent to the same horizontal line A boiling liquid of this composition produces a vapor of exactly the same composition, and



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7:

Most bomb threats are a hoax, but: A 5 to 10 percent are the real thing B 10 to 20 percent are the real thing C 20 to 30 percent are the real thing D 50 percent are the real thing

CHAPTER 10 Vapor/Liquid Equilibrium: Introduction -





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The Replace JDEINI option may be grayed out The Replace JDEINI option is accessible only if you are building an update package This is a good way to roll out changes to the development workstation JDEINI files After you choose Next on the Build Specification Options window, the Business Function Options window, shown in Figure 7-10, launches This window controls whether the business functions are built The specification XML/TAM files for business functions are always built If you are going to build the named event rules and DLLs, the Build Functions Options check box calls the Busbuild application, which compiles your business functions This window also has options that control the business function build After the Business Function Options window, the Compression Options window, shown in Figure 7-11, launches This window defines which directories are compressed during the package build process This option should be selected only for full packages

Figure 106 yx diagram forethaneln-heptane (Reproduced by permission from F H Barr-David, AIChE J, vol 2, p 426-427, 1956)

FIGURE 7-10 Business Function Options window (P9621/W9621N)

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the liquid therefore does not change in composition as it evaporates No separation of such a constant-boiling solution is possible by distillation The term azeotrope is used to describe this state3 The data for furan(1)lcarbon tetrachloride(2) at 30315 K (30 C) shown by Fig 108(c) provide an example of a system for which the P-xl curve lies above the linear P-xl relation The system shown in Fig 108(d)for ethanol(l)/toluene(2) at 33815 K (65 C) exhibits positive departures from linearity sufficiently large to cause a maximum in the P-xl curve This state is a maximum-pressure azeotrope Just as for the minimum-pressure azeotrope the vapor and liquid phases in equilibrium have the identical composition

High explosives are usually detonated by a blasting cap; however, explosives can also be detonated by: A A time-safety fuse B Gasoline C Matches D Detonation/priming cord

3~ compilation of data for such states is given by J Gmehling, Azeotropic Data, John Wiley & Sons, Inc, New York, 1994

FIGURE 7-11 Compress Options window (P9621/W9621M)

Figure 107 P T diagram for methanollbenzene (Redrawn from Chem Eng Sci, vol 19, J M Skaates and W B Kay, "The phase relations of binary systems that form azeotropes," pp 431-444, copyright 1964, with permission from Elsevier Science Ltd, Pergamon Imprint, The Boulevard, Langford Lane, Kidlington OX5 IGB, UK)

In a nonelectric firing system, the activation source would usually be: A Heat or flame B AC or DC current C Blasting machine D None of the above

If you compress the update packages, you will receive errors when deploying them to client workstations The only time that you should compress an update package is when using the product packaging tools Table 7-1 lists the options on the Compression Options window After you click Next in the Compression Options window, the Package Build Revisions window, shown in Figure 7-12, is displayed Here, you review the definitions for your specification build, business function build, and compression option build If you are satisfied with the options you have chosen, click the End button, not the Cancel button If you click the Cancel button, you will lose all your current definitions When you click the End button, you are taken back to the Work With Packages window On the Work With Packages window, select your package name and click the Activate/Inactivate button

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How to extract text from a PDF file in C#, VB.NET | WinForms - PDF
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