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The data given in Table 7.30 are typical for each dye class. There are, within each class, subclasses that have variances in application procedures (e.g., different pH, temperature, salt requirements). Also the dyeing method and substrate have in uence. Therefore, there is a large variation in these reported values. The following summarizes typical wastewater characteristics observed from various dye classes, as reported in [1]. One particularly noteworthy feature of these data is the extremely large variations that occur. This is typical of textile wastewater, which is highly variable from mill to mill, season to season, and so forth. There is signi cant interest in the use of natural dyes to reduce the environmental impact of dyeing processes. These are not in widespread use and suffer from several disadvantages. The shade range that can be produced with natural dyes is very limited. They are useful primarily for natural, not synthetic, bers. The fastness, especially to light, of many natural dyes is inferior. The cost in many cases is high. The pollutant characteristics of natural dyes are not well known. Many traditional natural dyes required mordants (copper or iron) for application to natural bers. In many cases, the dye af nity is low. Nevertheless, these represent a signi cant possibility for improvement and are under study at this time.



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For example, if a conventional solvent-borne auto basecoat used in 1970 had a nonvolatile content by volume (NVV) of 30%, then a basecoat used in 1980 at an NVV of 45% may have been called a HSSB basecoat [4(k)] However, by 1990 it is doubtful that a NVV of 45% would be called HSSB, and a NVV value of 55% might be needed to quality as HSSB The moving target aspect of HSSB status can give a misleading picture of the effort to reduce emission by changing to high-solids systems Consultants report that in 1994, 66% of the coatings volume used for OEM product nishes was solvent borne and the LSSB:HSSB breakdown was 45 to 21% By 1999, the solvent-borne portion of OEM paint was down to 45% and the LSSB:HSSB split was 23 to 22% The 1994 1999 comparison for HSSB (21 vs.





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22%) appears to indicate very little change to high-solids use, but in fact the change in highsolids de nition over time may contribute to the smallness of the apparent change to HSSB Of course, part of decrease from 66% LSSB coatings in 1994 to 45% in 1999 re ects changes to waterborne and powder coatings as well as to HSSB coatings During the early years of regulation in the United States, molecular weight reductions made in binder component to increase the solids content were very substantial Air quality regulations came later in Europe and Japan, and the regulations were not so sweeping These differences caused an entirely different course of binder development for OEM automotive coatings in the United States versus the rest of the world In the 1960s and early 1970s the dominant crosslinkers for automotive coatings worldwide were polymeric (actually oligomeric) butylated melamine formaldehyde (MF) resins [38].

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These resins were quite viscous To facilitate handling, they were diluted by addition of about 20 to 30 wt % solvent, often n-butanol In the United States, suppliers of MF resins developed methylated and mixed (methyl/butyl) ether crosslinkers of very low molecular weight (approaching monomeric) These resins were so much lower in viscosity that they did not require any solvent for handling [38] The high-solids MF resins were very reactive in the presence of p-toluene sulfonic acid catalysts [39] Use of these high-solids MF resins in the United States resulted in large decreases in solvent content of automotive coatings Reduction in the molecular weights of the acrylic polol co-reactants used with high-solids MF resins resulted in further solvent reductions When Japanese companies such as Honda and Toyota opened assembly plants in the United States (the so-called transplants), the Japanese paints could not be used here due to high solvent content.

Each major Japanese auto painter supplier negotiated an agreement with a US auto paint company to supply their transplants in the United States Agreement was never reached about which paint had better performance, but Japanese technical personnel in charge of coating at the transplants accepted the high-solids US systems as a necessary evil Use of thermoset crosslinking to build up molecular weight is a much-used strategy to permit use of low-molecular-weight binder components to start Several studies have explored the possibility of carrying this approach to the point of formulating zero-VOC thermoset liquid coatings Blank [14] recently summarized.

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