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20-623 High Consistency Applications (Cm > 020) At high mass concentrations, little or no free water is present in suspension The mixing strategy used is to expose as much damp ber surface to chemical as possible In high consistency oxygen deligni cation systems, ber is uffed to generate the ber surface area using aggressive mixers designed to disrupt the high consistency ocs These mixers are similar to re ners (see the plate pattern of the AB Nilsen mixer in Figure 20-21a) and apply tremendous power to the suspension Chemical can be added during mixing (usually, for liquids), or the uffed suspension can be transferred to a tower were contact with a gaseous chemical (eg, oxygen) can be maintained Ozone deligni cation can also be achieved in a high consistency operation Here, intimate contact with ber must be achieved quickly The Union Camp Corp.





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developed (White et al, 1993) a mixer/contactor based on a peg mixer design to create a dispersion of high consistency ber in the gas phase (Figure 20-21b) Again, the goal was to create ber surface area Ozonation proceeds through a shrinking core process (Bennington et al, 1999) Fibers that are not exposed to ozone are not bleached For liquid mixing, kneader-type mixers can be used These squeeze the suspension to transfer liquid between regions in the suspension Again, the high consistency of the suspension necessitates expenditure of considerable energy during the mixing process 20-624 Overview of Mixer Characteristics The wide range of mixers used in pulp bleaching applications can be characterized using a number of parameters The residence time determines the extent of exposure to mixing action and places an upper limit on the macroscale mixing that might be achieved.

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The power dissipated during mixing determines if the suspension will be mixed under turbulent conditions, and if oc disruption is likely Finally, the energy treatment gives an indication of the extent of mixing achieved in a given application Table 20-4 summarizes these parameters for laboratory mixers (used for bench scale bleaching studies) and for a range of industrial mixers Although these parameters are indicative of overall mixing performance, they do not account for the different ef ciencies often observed between mixers A number of observations can be made based on these data The rst observation is that energy expenditure increases with suspension mass concentration At low consistency, energy expenditure is typically 4 MJ/t At medium consistency, this varies between 4 and 40 MJ/t Although it is expected that mixing quality will improve with increased energy treatment, about 10 MJ/t is used by a wide range of mixers that achieve uidization.

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For high consistency mixers, energy treatment rises signi cantly The rate of mixing can be estimated.

To keep the discussion simple we first restrict the theory to leptonic weak interactions (for much of the remainder of this chapter we follow the presentations of Abers and Lee, 1973, and Quigg, 1983, Ch. 6).

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