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A photovoltaic electric system consists of photovoltaic modules, an electronic converter, a controller, and a bank of batteries Each module is made of photovoltaic cells connected in series, parallel, or series/parallel, as part of a panel supported by a mechanical structure A power converter may be used to regulate the ux of energy from the panel to the load so as to assure energy quality within certain limits The electricity converted from solar modules should be stored in banks of batteries of high capacity to make the overall system feasible economically The bank of batteries should store enough energy to minimize the night and/or low-light-intensity periods Maintenance of the modules should be limited to a wipe with a damp cloth, always using maximum care Getting leaves or deposits on the panels should be avoided because these are very sensitive structures.

The electric system should be installed in the following way: 1 Provide equipment grounding with a copper pole ground busbar of at least 2 m in length 2 Connect the negative conductor, usually black in color with an alligator claw, to the ground bar 3 Connect the other end of the negative cable, black in color, to the battery s negative terminal 4 Connect the negative conductor of the solar module to the negative pole of the electric fence equipment 5 Connect the positive conductor of the solar module to the equipment s positive pole 6 Connect the positive cable of the electric fence to the positive terminal of the battery 7 Connect the equipment s electric discharge conductor to the galvanized wire of the fence Several other aspects should also be considered at the design stage of a photovoltaic-based power supply system [14 18]: 1 2 3 4 5.

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6 7 The site should be open, without constant shadows for the solar light Use one or more solar modules Use structures or a support of aluminum Use a load controller Use a bank or set of batteries Consider using an indicator of the level of battery charge Use points of load consumption..

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degradation, the relative as well as the absolute con gurations of three stereogenic centers (C-1, C-3, and C-4) were postulated to be as shown (Figure 6-11) by biogenetic correlation and remained to be assigned unambiguously. Both 182 and 239 have been shown to exhibit signi cant cytotoxic antitumor activities against several human tumor cell lines. Pseudoplexaural (183) and pseudoplexauric acid methyl ester (184) have also been found in other Caribbean marine species Eunicea succinea (sea wip) and gorgonian Eunicea mammosa, respectively, and their structures were determined by spectroscopic analysis and chemical correlation with natural pseudoplexaurol (182). Epoxy alcohol 182 was assumed to be a logical biosynthetic precursor of 239, but attempts to synthesize lactone 239 from epoxy alcohol 182 via pseudoplexauric acid intermediate failed (Scheme 6-28).117 A recent successful translactonization of euniolide to crassin (236), which was reported by Rodr guez et al.,118 using aqueous alkaline hydrolysis under the assistance of sonication (Scheme 6-29) implies a possible conversion of 182 to 239 (Scheme 6-30). Synthetic studies on the closely related natural cembranolides bearing a 3, 4epoxy and/or lactone functions, such as crassin (240), euniolide (242), and isolobophytolide (243), have been conducted over the past decades by several groups (Figure 6-11).119 124 Liu et al. have reported on the total synthesis of 182 and 239 to verify their structural relationship and to con rm the relative and absolute con gurations.125 The overall strategic plan involves (1) chemical conversion of epoxy alcohol 182 to lactone 239 via an intramolecular lactonization, (2) construction of the 14-membered cembrane ring with geometrically de ned double bonds and substituents, (3) implementation of C-1 stereogenic center via a readily available chiral pool (i.e., Slimonene), and (4) introduction of chiral epoxide functionality via a Sharpless

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