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For the selective hydrogenation of alkynes to alkenes and, if possible, to cis olefins, palladium is by far the most selective metal. 6 ,81,88,89 Some nickel catalysts also appear to exhibit reasonable selectivity.81,90 In practice, palladium is always used in conjugation with different modifiers to increase selectivity. A highly selective palladium catalyst supported on CaC03 poisoned with lead acetate is known as the Lindlar catalyst. 91 ,92 By adding a nitrogen base to the reaction mixture, a sudden break in the rate of hydrogen consumption generally occurs after the adsorption of 1 mol of hydrogen. Low temperature and pressure are also recommended to achieve optimal selectivity. Palladium modified with Pb or Hg and used in transfer hydrogenation,93 the P-2 nickel catalyst prepared by the reduction of nickel acetate with NaBH4,90 and a Pd-Hg-on-Si0 2 catalyst prepared by a novel method (treatment of silica gel-immobilized silyl hydride with PdCl 2 then Hg 2S04)94 also ensure similar selectivities. A simple alternative to the Lindlar reduction process has been recognized. 95 The palladium(II) acetate-catalyzed polymerization of triethoxysilane in water produces finely divided palladium metal dispersed on a polysiloxane matrix with concomitant hydrogen evolution. Addition of (EtOhSiH to the mixture of an alkyne and all other necessary constituents allows facile and selective reduction of the alkyne without an external hydrogen source:



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Listing 17-6 defines the SHELL_TMPL string template, which replaces the old PAGE_TMPL now with slots to be filled with the list of subscriptions, as well as the feed entries filtered for display. Be sure to tailor this to fit your site design, adding whatever masthead and header elements you want.

The list in the Pattern Brush Options dialog box allows you to choose from four existing patterns instead of the selected artwork: None, Original, Polka Dot Pattern, and Waves Pattern. Any pattern in your document is listed here.

Understanding Dreamweaver Library basics Making and inserting Library items Managing your Dreamweaver Library Dreamweaver Technique: Building a Library Item Updating your Web sites with Libraries Dreamweaver Technique: Applying and Modifying Library Items Using server-side includes





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1. From the Server Behaviors panel, choose Update Record. The Update Record dialog box appears, as shown in Figure 23-16. 2. From the Update Record dialog box, choose a connection from the Connection drop-down list. If you need to establish a new connection, click Define. 3. Select the data table from the Table to Update list. 4. Choose the data source on which to base your update from the Select Record From list. 5. Select the key field from the Unique Key Column list. Dreamweaver attempts to detect whether the field is a number type and, if so, it selects the Numeric option. 6. Enter the path to the destination page in the After Updating, Go To field; or click the Browse button to locate the file. 7. Select the name of the form to be used from the Get Values From list. If there is only one form on the page, the form is preselected.

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If you really want to try landing a plane in a flight simulation game with your mouse or keyboard, feel free. But if you plan to spend a significant amount of time playing modern games, you re probably going to want to pick up the appropriate controllers for the games you prefer. Most controllers are USB, which means that they ll work just as well on your iMac as they would on a Windows PC. If you do bring home a controller that doesn t seem to work, download a copy of USB Overdrive ($20, www.usboverdrive.com), which enables you to program the buttons (and other controls) on any USB device.

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If desired, select a different option from the Document Type (DTD) list. When you re finished, click OK to close the Preferences dialog box. 2. After you perform the preceding step, you re done. To create a new default document, simply press Ctrl+Shift+N (Windows only). If you turned off the Show New Document Dialog On Ctrl+N option, you can also press Ctrl+N (Command+N).

3. Click the Crop button in the upper left corner of the viewer. iMovie displays green cropping handles and a frame in the viewer (see figure 5.12) and adds a red dot to the Playhead on the clip.

Table 9.21 shows that there are 8 pairs (z1 z2) if Dy (0, 0, 0, 1) 1; 03 The entry in Table 9.22 corresponds to 37 z1 (0, 0, 0, 0, 1, 1), z2 (1, 1, 0, 1, 1, 1) with sum (1, 1, 0, 1, 0, 0);

n previous versions of Flash Player, there was no built-in mechanism for uploading and downloading files to and from a server. Instead, you had to create workarounds for those tasks, using browser pop-up windows, DIVs, and such. However, with Flash Player 8, you can upload and download files directly from Flash Player using the new FileReference and FileReferenceList classes.

As with the inspectBehavior() function, the array for the function call string is one element longer than the number of arguments the initial array element is the function name itself.

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