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This section provides a number of examples to illustrate approaches to the identi cation of unknown organic materials by using infrared spectroscopy. First, an example of the use of the technique in identifying an organic compound containing a number of functional groups is provided. Citronellal is the terpenoid responsible for the characteristic aroma of lemon oil, and is used in perfumes and as a mosquito repellent. The infrared spectrum of citronellal is shown in Figure 4.11. At the higher-wavenumber end of the spectrum, the C H stretching region provides important information about the citronellal structure. This region is intense, hence indicating the presence of a number of C H groups in the structure. Distinct C H stretching modes at 2800 and 2700 cm 1 appear at wavenumbers characteristic of aldehydes. In addition, a strong band at 1730 cm 1 con rms the presence of an aldehyde group. The other C H stretching modes appear in the 3000 2900 cm 1 range and can be attributed to aliphatic C H stretching. The lack of bands at wavenumbers greater than 3000 cm 1 suggests that there is no aromatic group in the citronellal structure. The structure of citronellal is illustrated in Figure 4.12.



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There are structural problems related to nancing solar energy, primarily because of the high installation costs, lack of government nancial assistance, amount of time needed to gain the return of initial installation cost, and the belief that only large power plant installations can manage the world s energy problems There are, however, real opportunities to be sought by people with long-term vision Three general sources of capital are available for a renewable power project: equity, debt, and grant nancing An equity investment is the purchase of ownership in a project A debt investment is a loan to the project For example, in the purchase of a house, the person buying the house is the equity investor, and the mortgage is the debt [19 23].





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Since most solar power projects cannot compete with conventional fossil power technologies today, a number of organizations have grant nancing to help buy down the noneconomic portion of the project These grants typically are made available to help account for environmental, developmental, and economic externalities that would not otherwise be accounted for during a normal competitive project selection [20] One example is the contribution of solar thermal electricity generation to climate change, which can be assessed by calculating the greenhouse gas costs (GGCs) incurred during the provision of services and production of materials needed for the construction and operation of solar power plants Both process and input/output analyses are able to yield GGCs for solar-only plants with a typical uncertainty of about 25%, at a moderate level of input data detail The uncertainty of the GGCs for hybrid systems decreases with increasing fossil share.

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If it has not been done before this point, make sure that the product documentation for the products is reviewed and that it is sufficient to meet the needs of the project teams. Also, review the support lists and online forums that cover the product to get an impression of the experiences others have had with the product. What if none of the products meets all of your needs In that case, you need to determine which products come closest to meeting those needs and then select those products for further evaluation. If all of the products are missing a required feature, you might have to start investigating to see if there s another type of product somewhere that you can acquire to cover that feature. 3. The third step is the testing process, where you make certain that products you re interested in actually do meet your needs. Testing involves acquiring and installing the products and then creating a typical application scenario that exercises the features that the project is most dependent upon. This may be a proof of concept application or a technical prototype that is intended to exercise or demonstrate specific features. Some tests may involve performance measurements, while others may only demonstrate that a certain feature works as expected. At a minimum, pass or fail information for specific tests should be captured and recorded. The amount of time spent testing must be in proportion to the overall project size.

A unique attempt to conduct a polygraph study in a realistic setting and maintaining certainty about the ground truth was made by Ginton, Daie, Elaad, and Ben-Shakhar (1982) The participants in this study were 21 Israeli policemen who took a paper-and-pencil test that was presented as a requirement for a police course in which they were enrolled They were asked to score their own tests, which provided an opportunity to cheat by revising their initial answers However, the test answer sheets were chemically treated so that cheating could be detected It turned out that seven out of the 21 participants cheated Later, all were told that they were suspected of cheating They were offered a polygraph examination, and were told that their future careers in the police force might depend on the outcome of this examination.

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