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These sphotoisomerizations usually have picosecond timescales (Lednev et al, 1996; Kobayashi et al, 1979) Alternately, azos will thermally reconvert from the cis into trans state, with a timescale ranging from milliseconds to hours, depending on the substitution pattern and local environment More speci cally, the lifetimes for azobenzenes, aminoazobenzenes, and pseudo-stilbenes are usually on the order of hours, minutes, and seconds, respectively The energy barrier for thermal isomerization is on the order of 90 kJ mol 1 (Brown and Granneman, 1975; Haber eld et al, 1975) Considerable work has gone into elongating the cis lifetime, with the goal of creating truly bistable photoswitchable systems Bulky ring substituents can be used to hinder the thermal back reaction For instance, a polyurethane main-chain azo exhibited a lifetime of 4 days (thermal rate constant of k=2.



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attroff()affects only the text displayed after the attroff() function is issued. It does not affect all text on the screen at once. To turn off all attributes with attroff(), each attribute must be specified individually; you cannot use A_NORMAL with attroff() to reset all text attributes back to normal. (See attrset().) Removing a COLOR_PAIR attribute with attroff() restores the text to normal (white on black) text. So if you set one COLOR_PAIR attribute, then apply a second COLOR_PAIR attribute, removing the second COLOR_PAIR does not restore the first COLOR_PAIR. You must re-apply the COLOR_PAIR using an attron() function. Apparently removing a COLOR_PAIR attribute with attroff() also removes all other text attributes. attroff() and attr_off() are pretty much identical, save for the NULL argument required in attr_off(). (In NCurses, you ll mostly find underscores used by functions that manipulate wide characters.) Attributes are set by either the attrset() or attron() functions. Attributes affect the output of the addch(), addstr(), and printw() functions. Also refer to the Notes for attrset().





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attroff(A_BOLD);

8 10 6 s 1, at 31C) (Lamarre and Sung, 1983), and an azobenzene parasubstituted with bulky pendants had a lifetime of 60 days (ko2 10 7 s 1, at room temperature) (Shirota et al, 1998) The conformational strain of macrocylic azo compounds can also be used to lock the cis state, where lifetimes of 20 days (k=59 10 7 s 1) (Norikane et al, 2003), 1 year (half-life 400 days, k=2 10 8 s 1) (Rottger and Rau, 1996; Rau and Roettger, 1994), or even 6 years (k=49 10 9 s 1) (Nagamani et al, 2005) were observed Similarly, using the hydrogen bonding of a peptide segment to generate a cyclic structure, a cis lifetime of B40 days (k=29 10 7 s 1) was demonstrated (Vollmer et al, 1999).

wattroff(help,COLOR_PAIR(1));

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Note that we use the NON_RETAIN policy, which tells the POA not to maintain an active object map for the mapping between OBJECT ID and servant: this differentiates the servant locator from the servant activator, as the servant locator has to keep track of the OBJECT ID-to-servant mapping itself. The servant locator registration and object reference creation is similar to that for the servant activator. One way to apply servant managers is to perform POOLING, meaning the servant manager manages a pool of servants. A servant locator looks up a servant from the pool in preinvoke and hands it to the POA.

This statement removes the text color assigned to COLOR_PAIR 1 from any new text displayed in the window help.

Of course, one can also generate a system that starts in the cis state and where isomerization (in either direction) is completely hindered For instance, attachment to a surface (Kerzhner et al, 1983), direct synthesis of ringlike azo molecules (Funke and Gruetzmacher, 1987), and crystallization of the cis form (Hartley, 1938, 1937) can be used to maintain one state, but such systems are obviously not bistable photoswitches A bulk azo sample or solution under illumination will achieve a photostationary state, with a steady-state trans cis composition based on the competing.

attroff(A_BOLD | A_REVERSE);

24.09.2004 21:13

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