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supramolecular helix at will, by changing the incident light handedness. There are many other examples of photocontrol of supramolecular order. The pitch of a cholesteric LC can be modi ed by isomerization (Sackmann, 1971). Biomacromolecular variants abound (Willner and Rubin, 1996). Azo-modi ed polypeptides can be photoswitched between ordered states (a-helix or b-sheet) and a random coil (Everlof and Jaycox, 2000; Fissi et al., 1996; Yamamoto and Nishida, 1991). The duplex of modi ed DNA can be reversibly switched (Asanuma et al., 2001), and the catalytic activity of histidine can be controlled (Lee and Ueno, 2001). Photoisomerization can also affect self-assembly behavior at the domain level. On irradiation, one can induce a phase change (Aoki et al., 2000), a solubility change (Arai and Kawabata, 1995; Yamamoto et al., 1990), crystallization (Ebralidze and Mumladze, 1990), or even reversal of phase separation (Ef ng and Kwak, 1995). The critical micelle concentration (cmc) and surface activity can also be modi ed (Yang et al., 1995). In an amphiphilic polypeptide system, selfassembled micelles were formed in the dark and could be disaggregated with light (Higuchi et al., 1994). When allowed to assemble as a transmembrane structure, the aggregate could be reversibly formed and destroyed using light, which allowed for reversible photoswitching of ion transport (Higuchi et al., 1995a). Related experiments on methacrylates (Chen et al., 1997a; Angiolini et al., 1995) and polypeptides (Sisido et al., 1991b) showed that a polymer s chiral helix could be reversibly suppressed on irradiation. In a series of polyisocyanate polymers, it could be selected whether irradiation would suppress or increase chirality (Muller and Zentel, 1996; Maxein and Zentel, 1995).



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CORBA Technology Projection client s current priority. This means that different operations on the same remote object can subsequently be invoked at different priorities.

14, Appendix B, border(), hline(), vline()





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(Deff,dark) and under UV irradiation (Deff,UV) were estimated to be 9.5 10 17 m2 s 1 and 1.7 10 16 m2 s 1, respectively. These values are much smaller than the effective diffusivity of FDM in Brij 56 templated photoresponsive nanocomposite membranes (Deff,dark = 1.1 10 14 m2 s 1, Deff,UV = 1.6 10 14 m2 s 1). As the pore size and probing molecule size are comparable in the two cases, the pore accessibility plays a major role. It was demonstrated that the photoresponsive nanocomposite membrane had a BCC mesostructure whereas the photoresponsive nanocomposite particles had an onionlike lamellar structure. Only the defects located on the particle surfaces could provide the pathway for uptake and release of OBN probe molecules, which lowered the effective diffusivity considerably.

can_change_color()

The can_change_color() function determines whether or not a terminal can re-define its color set. If so, then the color_content() function can be used to create new color values for use with NCurses various text color attribute functions.

CORBA::PolicyList policies (1); policies.length (1); policies[0] = rtorb->create_priority_model_policy ( RTCORBA::CLIENT_PROPAGATED, DEFAULT_PRIORITY /* For non-RT ORBs */); PortableServer::POA_var my_poa = root_poa->create_POA ("My_POA", PortableServer::POAManager::_nil (), policies); // Activate a servant my_poa->activate_object (my_servant);

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13.3.5. Reversible Photoswitching Liquid-Adsorption of Azobenzene-Modi ed Mesoporous Silica Materials

bool can_change_color(void);

can_change_color() returns a Boolean value, TRUE or FALSE, depending on whether the terminal can redefine its colors.

Seki et al (1993) developed a command surface concept, which uses the azobenzene derivatives bound on the Langmuir Blodgett (LB) lms to control the orientation of the liquid crystal molecules on the lm surfaces by the photoswitching of the azobenzene moieties Maeda et al (2006) extended this concept to control the adsorption properties of mesoporous silica materials by reversible photoswitching of the azobenzene moieties anchored on the pore surfaces A UV/visible spectra study con rmed that the azobenzene moieties isomerized from trans to cis conformation under UV (l = 365 nm) light irradiation at 101C and the reverse isomerization (cis to trans) occurred under visible (l = 436 nm) light irradiation Both isomerization processes saturated after 3 5 min.

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