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ch is an NCurses chtype variable, which can represent a single character or character and attribute combination. See Appendix C for more information. Refer to the mv, mvw, and w entries elsewhere in this appendix for information on the win, y, and x arguments.



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Characters placed at the last column cause the cursor s location to drop to the next row. Characters placed at the last column of the last row do not advance the cursor unless scrolling is enabled for the window, in which case the window will scroll up one line. See scrollok(). The addch() function interprets some characters specially:

Figure 13.6. Representative TEM images of mesoporous silica thin lms. Insets are the corresponding electron diffraction patterns.





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\t. the tab character advances the cursor to the next tab stop, which is set every eight columns in a window. This value can be reset by using the TABSIZE variable; see TABSIZE. \n. the newline character erases all text from the cursor s position to the end of the line (see clrtoeol()), then drops the cursor down to the next line. If the cursor is on the last line of the screen, then the window s contents are scrolled, but only if scrolling is enabled for that window; see scrollok(). \r. the carriage return moves the cursor to the start of the current line (column zero). It will not erase to the end of the line. \b. the backspace character moves the cursor back one notch. It does not erase. When the cursor is at the start of a line (column zero), the backspace does nothing.

24.09.2004 19:58

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composition of surfactant, silica, water, acid, and solvent. After surfactant removal by calcination or solvent extraction, mesoporous silica materials are formed (Fig. 13.6). EISA provides a highly controllable approach to fabricate nanoporous lms and particles. The fast process, easy integration of nanoporous lms into devices, and controllable properties (pore sizes, pore surface chemistries, pore arrangements, and porosity) are especially suitable for the application of nanotechnology in industry.

Control characters other than \t (^I), \n (^J), \r (^M), or \b (^H) are displayed using the ^c notation by addch(). This effectively puts two characters to the screen, both the ^ and the control character s corresponding key value, such as G for ^G. See unctrl() for more information. You can also use addch() to place ACS (Alternate Character Set) characters to the screen. Refer to Appendix B for more information on those characters.

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Concept of Stimuli-Responsive Nanocomposite Materials. To expand the range of applications as well as create new properties, various organic functional groups have been covalently incorporated onto the pore surfaces of mesoporous materials, including phenyl, octyl, aminoalkyl, cyanoalkyl, thioloalkyl, epoxyl, and vinyl groups (Nicole et al., 2005). However, these modi cations have provided mainly passive functionalities, such as controlled wetting properties, reduced dielectric constants, or enhanced adsorption of metal ions. By comparison, materials with stimuli-responsive functionalities would enable properties to be dynamically controlled by external stimuli, such as pH, temperature, or light. The concept of stimuli-responsive nanocomposite materials was proposed by Brinker and coworkers (Liu et al., 2003a; Fig. 13.7). Incorporation of covalently bonded, switchable ligands as pendant groups (as opposed to bridging groups) within a porous (rather than a layered) framework is expected to result in nanocomposites in which the pore size, surface area, and adsorptive properties are externally controllable. In such synergistic nanocomposites, the 3-D organization of the responsive ligands allows transduction of photo, chemical, or thermal energy into a useful mechanical response of interest for molecular valves or gates. In addition, the rigid framework could serve to enhance the mechanical, chemical, and thermal stability of the responsive moieties, fostering their integration into devices. As described earlier, switchable azobenzene derivatives are promising candidate molecules for the synthesis of photoresponsive nanocomposite materials. To best utilize photoisomerization to accurately control pore size, azobenzene ligands need to be anchored to the pore surfaces of a uniform mesostructure with monosized pores. This allows the rigid inorganic framework to precisely position azobenzene ligands in 3-D con gurations where switching results in a well-de ned change in pore size.

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