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Photoresponsive behavior of the hybrid colloids depends on the composition and distribution of the components in the colloids (Deng et al., 2007). The hybrid colloid composed of BP-AZ-CA and PEAPE, whose preparation has been discussed in Section 5.3.4, is further discussed herein concerning its photoresponsive properties. As PEAPE and BP-AZ-CA contain HEAZ moieties and ACAZ moieties, the colloids can show photoinduced variation related to the azobenzenetype and pseudostilbene-type chromophores. Figure 5.16 shows the UV-vis spectra of the stable suspensions of the PEAPE/ BP-AZ-CA (1:1, wt:wt) hybrid colloids before and after UV light (365 nm) irradiation. For single-component colloids of PEAPE and BP-AZ-CA, the p p* transition bands (lmax) appear at 365 and 470 nm. For the hybrid colloids, the absorption bands at 365 and 455 nm can be assigned to the HEAZ and ACAZ moieties of the polymers. The new band appearing at 387 nm could be the absorption band because of the HEAZ/ACAZ charge-transfer complex. Upon the light irradiation, the absorption at 365 and 387 nm decreases gradually as the result of the trans-to-cis isomerization of the HEAZ chromophores. No variation is observed for absorption band at 455 nm because trans cis isomerization of the ACAZ moieties (a pseudostilbene-type chromophore) is too fast to be detected at the timescale given here (Rau, 1990). The relative absorbance can be given as At/ Aorigin, where Aorigin and At are the absorbance at 365 nm before the light irradiation and after the irradiation for different time periods. At/Aorigin can be used to indicate the relative amount of the trans isomers remaining at t time, and its variation represents the kinetics of the photoisomerization. The variations can



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slk_attron(A_UNDERLINE);

1.00 Absorbance (a.u.)

Here, the underline attribute is set in addition to any other attributes already defined for the soft labels.

A client invokes an operation on a remote object. Because the instance has moved from one server application to another, the LOCATION FORWARDER forwards the invocation to the server application where the remote object currently resides.

slk_attron(A_BOLD | A_BLINK);

0.25 300 400 500 Wavelength (nm) 600

This statement turns on the bold and (annoying) blink attributes, in addition to any other attributes previously defined, for the soft labels.





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E E E When a client performs an invocation using a particular ABSOLUTE OBJECT REFERENCE to a server application, the invocation will reach the INVOKER. If the INVOKER cannot resolve the target remote object locally, the INVOKER can delegate the invocation to a LOCATION FORWARDER. The LOCATION FORWARDER looks up the new location, represented as an ABSOLUTE OBJECT REFERENCE based on the OBJECT ID. The behavior that occurs after the new location has been resolved depends on the use case.

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 #include <ncurses.h> #define CENTER 1 #define LCOUNT 8 int main(void) { char labels[LCOUNT][19] = { Help! , File , Print , Text , Edit , Quick , Config , System }; char *text; int x; slk_init(0); initscr(); for(x=0;x<LCOUNT;x++) slk_set(x+1,labels[x],CENTER); slk_attron(A_BOLD); slk_refresh(); refresh(); getch(); endwin(); return 0; }

Figure 5.16. Variation of the UV-vis spectra of the colloidal dispersions induced by the UV light irradiation. The dispersions were obtained by adding water into a THF solution of PEAPE/BP-AZ-CA (1:1, wt:wt). Source: From Deng et al., 2007.

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Sample output: The labels appear in bold text (in addition to inverse/standout).

attron(), slk_attrset(), slk_attroff(), slk_color()

be best tted by the rst-order exponential decay function At =Aorigin A0 A1 exp t=T1 5:2

24.09.2004 20:04

slk_attrset()

where T1 is the characteristic time of the decay process. For comparison, the photoisomerization behavior of a stable dispersion of the PEAPE colloids can be obtained in the same way. Both experimental data and tting curves are shown in Fig. 5.17. T1 obtained from the curve tting are 43.4 and 37.3 s for the hybrid colloids and PEAPE colloids, respectively. Comparing with the monocomponent PEAPE colloids, the trans-to-cis isomerization rate is far slower for the hybrid colloids. The hybrid colloids can show photoinduced deformation, and deformation ability is dependent on the percentage of the BP-AZ-CA component in the colloids. The experimental conditions for the sample preparation and light irradiation are the same as those mentioned earlier. The colloidal spheres were exposed to the spatially ltered and collimated laser beam incident perpendicularly on the substrate surfaces. The morphologies of colloidal spheres were observed by TEM before and after the laser irradiation. For comparison, the hybrid colloids and the monocomponent colloids were studied by the same light irradiation condition.

The slk_attrset() function discards any previously defined attributes for the soft label keys and defines a new set of attributes. It is the soft label key counterpart of the attrset() functions.

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