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The method and understanding discussed in the foregoing sections can be used to construct colloidal spheres composed of more than one type of azo polymers (Deng et al., 2007). As a typical example, the azo polymers BP-AZ-CA and PEAPE (the chemical structure of the polymers can be seen in Figs. 5.1 and 5.2) have been selected to construct the hybrid colloids. According to the spectral characteristics, the azo chromophores in BP-AZ-CA and PEAPE, 4-amino-4u-carboxylazobenzene (ACAZ) moieties and 4-hydroxyl-4u-ethoxyazobenzene (HEAZ) moieties, can be classi ed as pseudostilbene- and azobenzene-type azo chromophores, respectively. The hybrid colloids can be prepared by dissolving the two polymers in THF and then gradually adding deionized water into the mixture. After the water content reaches some required value (60%, vol%), the structures formed in the suspensions are quenched by adding excess deionized water. The composition of the colloids can be adjusted by selecting different ratios of the two polymers. Figure 5.8 shows some typical TEM images of the colloids, which were obtained from the stable dispersions of PEAPE (Fig. 5.8a), BP-AZ-CA (Fig. 5.8b), and PEAPE/BP-AZ-CA (1:1, wt:wt) colloids (Fig. 5.8c). It can be seen from the images that all three systems can produce uniform colloidal spheres. The hybrid colloidal spheres seem to possess a more uniform shape compared with the monocomponent colloids. The DLS measurements were used to characterize the size of colloids in the stable suspensions of the colloids. For the colloids of PEAPE, BP-AZ-CA, and PEAPE/BP-AZ-CA (1:1, wt:wt), the average hydrodynamic radii (Rh) are 154, 102, and 111 nm. The hybrid colloids show an obviously lower polydispersity (0.061) compared with both the PEAPE colloids (0.138) and the BP-AZ-CA colloids (0.156). UV-vis spectroscopic study on the PEAPE/BP-AZ-CA colloid suspension shows characteristics of both types of azo



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The cursor on the virtual screen is set to 5, 5. And getsyx() reports 5, 5.

Figure 5.8. Typical TEM images of the colloidal spheres: (a) PEAPE, (b) BP-AZ-CA, and (c) PEAPE/BP-AZ-CA (1:1, wt:wt). Source: From Deng et al., 2007.

getsyx(), leaveok()

set_term()

10 Scattered light intensity (a.u.) 8 6 4 2 0 0

24.09.2004 20:04

The set_term() function determines which terminal to use for NCurses input and output functions. Used primarily in conjunction with newterm() when configuring unique terminal setups for NCurses.

20 40 Water content (vol%)

SCREEN *set_term(SCREEN *new);

constituents, such as LIFECYCLE MANAGER, PROTOCOL PLUG-INS, and so on, are specified at the CONFIGURATION GROUP level.

new is the name of a SCREEN pointer, returned by newterm().

Figure 5.9. Scattering light intensity as a function of the water content (vol%) for PEAPE, BP-AZ-CA, and PEAPE/BP-AZ-CA (1:1, wt:wt) dissolved in THF-H2O media. The scattered light intensity shown here is a ratio of scattered light intensity to incident light intensity. Source: From Deng et al., 2007.

This is the only function that manipulates SCREEN pointers. (The delscreen() function removes space allocated to the pointers.)

old = set_term(new);

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