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24a, at the rst step, 420-nm pulses lengthened the polymer with a force of 80 pN (I), then expanded mechanically to a restoring force of 200pN (II) UV pulses caused a contraction of the polymer chain (III) and the force on the polymer was reduced to 85 pN (IV) Finally, 420-nm pulses changed the system back to its original state From point II to III, the contraction of the polymer chain lifted the weight and thereby did mechanical work Fig 1324b describes the corresponding force extension The slope of the optical branches of the cycle are determined by the stiffness of the cantilever The work output of the system (shadow area in Fig 1324b) is the mechanical energy related to the contraction of the polymer The energy input needed to perform this mechanical work is light energy However, the ef ciency of energy conversion.



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The clearok() function modifies window behavior in NCurses. When switched on, clearok() forces the next call to refresh() to entirely erase the window and redraw it from scratch.

Related Concepts, Technologies, and Patterns established knowledge, and fields like P2P, Grid, or AOP are still emergent. We expect patterns for these fields to appear in the future.

Normally, the refresh() function merely updates those parts of the window that have been changed. But by switching on clearok(), a complete erasure and rewrite of the window is possible.

F0 Extension (b)

int clearok(WINDOW *win, bool bf);

win is the name of the window to erase and redraw. stdscr can be used for win to update the standard screen. bf is a Boolean value, either TRUE or FALSE. TRUE is used to activate erasing/redrawing for the named window; FALSE turns it off.





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Figure 13.24. Schematics of the single-molecule operating cycle. Points I IV in (a) represent the four states of an operating cycle. (b) The corresponding force extension plot. Source: Hugel et al., 2002. Reprinted with permission.

The screen isn t actually erased and redrawn until a refresh() or wrefresh() function is used. When the current screen, curscr, is used as the win argument, NCurses erases and redraws the entire screen from scratch at the next refresh(). Apparently erasing and redrawing the entire screen is visually distracting, but this must only be so with slower terminal speeds. (Refer to baudrate().)

clearok(stdscr,TRUE);

(Z = Wout/Win) is estimated to be 0.1 in this single-molecule device, which is relatively low for optomechanical applications. Other than the SAMs and azobenzene-containing organic polymers, azobenzene-modi ed hybrid polysilsesquioxane gels were also studied for their photomechanical responses. 13.4.2.2. Preparation of Azobenzene-Modi ed Polysilsesquioxane Gels. The BSUA molecules in highly concentrated solid states are very

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The statement causes the next call to refresh() to erase and redraw the standard screen, ensuring that what s shown in the screen matches memory.

dif cult to isomerize under UV irradiation because of the intermolecular hydrogen-bonding and p p stacking interactions. To avoid these interactions, the BSUA molecules could be diluted in an aerogel network, providing the extra volume (B127 A3) and exible framework needed for the isomerization of the azobenzene ligands. In the aerogel formation process, 15.3 mol% BSUA was diluted with 20.7 mol% bis(triethoxysilyl)ethane (BTE) and 64 mol% TEOS. BTE molecules with CH2CH2 bridges were used to increase the exibility of the gel frameworks. The gel was nally derivitized with hexamethyldisilazine (HMDS) to promote stability and exibility. Thin lms were deposited on the substrates by the casting or spin-coating of the gel dispersed in EtOH. The prepared thin lms exhibited reversible photo and thermal isomerization of azobenzene ligands as detected using UV/visible spectroscopy. As shown in Fig. 13.25, the absorbance of the p p* transition band of the trans isomer at 365 nm decreases under UV irradiation, and the corresponding absorbance of the n p* transition band of the cis isomer at 480 nm increases (Fig. 13.25 curve b), indicating the trans-cis isomerization of azobenzene ligands contained in the lm. Compared with BSUA in EtOH solvent, the n p* transition of the cis isomer in the gel lm exhibits a much higher absorbance, indicating a higher concentration of the cis isomer and a higher molar absorption coef cient (e), which is due to the steric effect. The reverse cis-trans isomerization was achieved when the lm was exposed to room light or heat (Fig. 13.25 curves c,d). The heat treatment at 1001C for 10 min even caused the 365-nm absorption band to exceed that of the asprepared lm, indicating that a certain amount of azobenzene ligands were in the

clearok(menu,FALSE);

Here, clearok() updating is disabled for the window menu. Any subsequent calls to refresh() update only changed parts of the screen.

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clearok(curscr,TRUE);

After executing this statement, the next call to wrefresh() forces the standard screen to be cleared and then redrawn from scratch.

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