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Perhaps of a range as wide as the interesting phenomena displayed by azo aromatic compounds is the variety of molecular systems into which these chromophores can be incorporated. In addition to LC media and amorphous glasses, azobenzenes can be incorporated into self-assembled monolayers and superlattices, sol gel silica glasses, and various biomaterials. The photochromic or photoswitchable nature of azobenzenes can also be used to control the properties of novel small molecules, using an attached aromatic azo group. A review will be presented here of the photochemical and photophysical nature of chromophores in host polymers, the geometric and orientational consequences of this isomerization, and some of the interesting ways in which these phenomena have been expolited recently to exert control over solution and biochemical properties using light. This photoisomerization can be exploited as a photoswitch to orient the chromophore (which induces birefringence), or even to perform all-optical surface topography patterning. These photomotions enable many interesting applications, ranging from optical components and lithography to sensors and smart materials.





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Overview of the Pattern chapters The three basic lifecycle strategy patterns have the following focus:

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In this text, as in most on the subject, we use azobenzene and azo in a general way: to refer to the class of compounds that exhibit the core azobenzene structure, with different ring substitution patterns (even though, strictly, these compounds should be referred to as diazenes ) There are many properties common to nearly all azobenzene molecules The most obvious is the strong electronic absorption of the conjugated p system The absorption spectrum can be tailored, via the ring substitution pattern, to lie anywhere from the UV to the visible red region It is not surprising that azobenzenes were originally used as dyes and colorants, and up to 70% of the world s commercial dyes are still azobenzene-based (Zollinger, 1987, 1961).

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STATIC INSTANCES are used to represent fixed functionality in the system. Their lifetime is typically identical to the lifetime of their server application. PER-REQUEST INSTANCES are used for highly concurrent environments. They are created for each new request and destroyed after the request. CLIENT-DEPENDENT INSTANCES are used to represent client state in the server. They rely on the client to instantiate them explicitly. The lifecycle strategies patterns make use of a set of specific resource management patterns internally: LEASING is used to properly release CLIENT-DEPENDENT INSTANCES when they are no longer used. LAZY ACQUISITION describes how to activate remote objects on demand. POOLING manages unused remote object instances in a pool, to optimize reuse. For state management, PASSIVATION takes care of removing unused instances temporarily from memory and storing them in persistent storage. Upon request, the instances are restored again. The patterns and their relationships are shown in the following figure.

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The geometrically rigid structure and large aspect ratio of azobenzene molecules make them ideal mesogens: azobenzene small molecules and polymers functionalized with azobenzene can exhibit LC phases (Mohlmann and van der Vorst, 1989; Kwolek et al, 1985) The most startling and intriguing characteristic of the azobenzenes is their highly ef cient and fully reversible photoisomerization Azobenzenes have two stable isomeric states, a thermally stable trans con guration and a metastable cis form Remarkably, the azo chromophore can interconvert between these isomers upon absorption of a photon For most azobenzenes, the molecule can be optically isomerized from trans to cis with light anywhere within the broad absorption band, and the molecule will subsequently thermally relax back to the trans state on a timescale dictated by the substitution pattern This clean photochemistry is central to azobenzene s potential use as a tool for nanopatterning.

Tossing Up Text One Stupid Character at a Time Pausing for a Side-trip Blurping Text The move() Function The Old Formatted Text Trick

Server Application instantiates STATIC INSTANCE LAZY ACQUISITION LIFECYCLE MANAGER instantiates PER-REQUEST INSTANCE Client instantiates CLIENT-DEPENDENT INSTANCE requires

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Azobenzenes can be separated into three spectroscopic classes, well described by Rau (1990): azobenzene-type molecules, aminoazobenzene-type molecules, and pseudo-stilbenes (refer to Fig 11 for examples) The particulars of their absorption spectra (shown in Fig 12) give rise to their prominent colors: yellow, orange, and red, respectively Many azos exhibit absorption characteristics similar to the unsubstituted azobenzene archetype These molecules exhibit.

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