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This reversed ordering of the absorption bands de nes the third spectroscopic class, the pseudo-stilbenes (in analogy to stilbene, phenyl C=C phenyl) The pseudo-stilbenes are very sensitive to local environment, which can be useful in some applications Especially in condensed phases, the azos are also sensitive to packing and aggregation The p p stacking gives rise to shifts of the absorption spectrum If the azo dipoles have a parallel (head-to-head) alignment, they are called J-aggregates, and give rise to a redshift of the spectrum (bathochromic) as compared with the isolated chromophore If the dipoles are antiparallel (head-to-tail), they are called H-aggregates and lead to a blueshift (hypsochromic) Fluorescence is seen in some aminoazobenzenes and many pseudo-stilbenes but not in azobenzenes, whereas phosphorescence is absent in all the three classes.



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attrs is the location of a variable of the NCurses type attr_t, a long int (the same as a chtype). It is used to store the attribute information read from window. Essentially attrs is a bit field and the bits in the field are set according to which attributes are active in the window. Appendix C describes the chtype bit field. pair is the memory location of a short int value used to store the color pair number used to color the window. The NULL placeholder represents the opts argument. opts is not defined presently but reserved for future use. Refer to the w prefix entry later in this appendix for information on the win argument.

The attrs argument is declared by using NCurses attr_t variable type:

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By altering the electron density, the substitution pattern necessarily affects the dipole moment, and in fact all the higher order multipole moments This becomes signi cant in many nonlinear optical (NLO) studies For instance, the chromophore s dipole moment can be used to orient with an applied electric eld (poling), and the higher order moments of course de ne the molecule s nonlinear response (Delaire and Nakatani, 2000) In particular, the strongly asymmetric distribution of the delocalized electrons that results from push pull substitution results in an excellent NLO chromophore..

attr_t ats;

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Here in this line of code, the variable ats is created from the attr_t type. Both the attrib and pair argument are memory locations. They can be represented by pointer variables or regular variables prefixed with the & unary operator. It s possible to replace either attrib or pair with NULL, in which case that particular chunk of information will not be returned by attr_get(). The pair value returns only the color pair number. It does not tell you which colors are assigned to that color pair number. For that tidbit you need to use the pair_content() function. In my experiments I ve been unable to get attr_get() to return both text and color attributes from a given window. The function seems to prioritize text attributes, such as A_BOLD, A_BLINK, and so on. But when those attributes are present along with color information, only the attribute values are returned. When the attributes are removed from the window, the color information is returned. (This is probably an effect of NCurses handling the ncv (no_color_video) capability of the terminal. When the terminal description says (with this capability) that colors do not mix with the given video attributes, it only uses the colors.) To specifically retrieve a window s background attributes, use the getbkgd() function. See getbkgd().

Key to some of the most intriguing results and interesting applications of azobenzenes is the facile and reversible photoisomerization about the azo bond, converting between the trans (E ) and cis (Z) geometric isomers (Fig. 1.3). This photoisomerization is completely reversible and free from side reactions, prompting Rau to characterize it as one of the cleanest photoreactions known. (Rau, 1990) The trans isomer is more stable by B50 kJ mol 1 (Mita et al., 1989; Schulze et al., 1977), and the energy barrier to the photoexcited state (barrier to isomerization) is on the order of 200 kJ mol 1 (Monti et al., 1982). Thus, in the dark, most azobenzene molecules will be found in the trans form. On absorption of a photon (with a wavelength in the trans absorption band), the azobenzene will convert, with high ef ciency, into the cis isomer. A second wavelength of light (corresponding to the cis absorption band) can cause the back-conversion.

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