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Matejka et al. synthesized several types of photochromic polymers based on a copolymer of maleic anhydride and styrene with azobenzene moieties both in the side chains and cross-links of the polymer network (Matejka et al., 1981; Matejka and Dusek, 1981; Matejka et al., 1979) . The photomechanical effect was enhanced by an increase in the content of photochromic groups, and the photoinduced contraction of the sample amounted to 1% for a polymer with 5.4 mol% azobenzene moieties. The photoinduced expansion of thin lms of polymers (4) containing azobenzene chromophores was explored in real time by single wavelength ellipsometry (Fig. 3.6; Tanchak and Barret, 2005). The initial expansion of the azobenzene polymer lms of thickness ranging from 25 to 140 nm was irreversible and amounted to 1.5% 4%. Subsequently, reversible expansion was observed with repeated irradiation cycles; the relative expansion was 0.6% 1.6%. Recent development of single-molecular force spectroscopy by atomic force microscopy (AFM) techniques has enabled quite successfully the measurement of mechanical force produced at a molecular level. Gaub and coworkers reported on a phototriggered polymer, which contains azobenzene units as part of the main polymer backbone (5; Adoc=1-adamantyloxycarbonyl) (Holland et al., 2003; Hugel et al., 2002). This key study demonstrates a photomechanical cycle using



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Identification Patterns To avoid performance bottlenecks and single points of failure, clients should use LOOKUP sparsely. For example, you should only register factory objects, in the sense of Factory Method [GHJV95] and Abstract Factory [GHJV95], and obtain further references through them. To further reduce the chances for failure, lookup services are typically replicated and/or federated across several hosts. Keeping the replicas consistent does incur a performance overhead, which is another reason for storing only a few important initial objects in the LOOKUP service. This pattern was originally documented in POSA3 [KJ04].

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Figure 3.6. Schematic representation of photoexpansion effect in the thin lms. Source: Tanchak and Barret, 2005.

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a single azobenzene polymer molecule (Fig. 3.7), representing the rst experimental work using photomechanical energy conversion in a single-molecule device, in which a polymer is covalently coupled to an AFM tip and a glass slide. The azobenzene units are reversibly switched at two distinctly different wavelengths between an extended trans and a contracted cis con guration. Applying focused UV light (l=420 nm) to the glass substrate having the polymer bound to it results in stretching of the polymer since its conformation is switched to the alltrans state. Subsequent irradiation with light of lmax=356 nm causes relaxation of the polymer and conversion to the all-cis conformation. The material can be repeatedly cycled between these two states, even when an external load is put on the AFM tip. The mechanical work performed by the azobenzene polymer strand by trans cis photoisomerization was approximately 4.5 10 20 J. This mechanical work at the molecular level results from a macroscopic photoexcitation, and the real quantum ef ciency of the photomechanical work for the given cycle in their AFM setup was only on the order of 10 18. However, a maximum ef ciency of the photomechanical energy conversion at a molecular level can be estimated as 0.1, if it is assumed that each switching of a single azobenzene unit is initiated by a single photon with an energy of 5.5 10 19 J (l=365 nm) (Holland et al., 2003; Hugel et al., 2002).

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The three patterns introduced in this chapter are used for locating objects. The use of the OBJECT ID pattern has already been implicitly shown in the sequence diagram examples in 3, Basic Remoting Patterns, where the OBJECT ID was used by the INVOKER to find the target remote object in its list of instances. The following sequence diagram shows how a server application registers the reference of a remote object in LOOKUP and how a client uses the lookup service to retrieve this reference. The ABSOLUTE OBJECT REFERENCE of the lookup service has been configured manually, both in the server application and in the client application. Both server application and client use a framework facade to retrieve the initial reference to the lookup service. Here the framework facade acts a utility class providing access to the middleware s core features. The lookup service is itself implemented as a remote object, offering the operations bind for registering remote objects and lookup for looking up ABSOLUTE OBJECT REFERENCES of remote objects.

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