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Earlier investigations revealed that PVAs possessing an Az-containing side chain show large photoinduced area changes on a water surface (Seki et al., 1998, 1996). In a particular case, the monolayer exhibits ca. threefold expansion and contraction by alternating illumination with UV and visible light in a fully reversible manner. This effect can be explained by the polarity change of the Az unit. The molecular packing model exactly explains the degree of area changes, indicating that the macrosize effect correctly re ects the molecular events. In situ X-ray re ectivity (XR) analysis on the water surface by Kago et al. (1999) revealed the actual thickness change on water. Quite recently, Ohe et al. (2007) directly evaluated the photomodulated orientations of the individual chemical bonds of this polymer in detail by sum frequency generation spectroscopy. It is anticipated that, when one of the blocks is composed of a photoresponsive segment (area-variable component) in the monolayer state, the change in the area fraction of the blocks may alter the MPS nanostructures. By utilizing the photomechanical response of the monolayer mentioned earlier, such light-induced modulations in the 2-D nanostructures have been actually attained (Kadota et al., 2005) (Fig. 8.16). The trans and cis isomeric states of Az result in dot and strip structures, respectively, of the Az-containing domain in a reversible manner. This tunable behavior of the morphology provides an important aspect on the chain conformation on water. The middle block of poly(ethylene oxide) (PEO) chain should adopt predominantly loop conformations rather than bridge ones. This fact coincides with the tendency of segregation rather than interpenetration of polymer chains in the 2-D state (Sato et al., 1998). At highly humidi ed state, the morphological changes on a hydrophilic solid surface of mica are also observed



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typeahead(stdio);

.NET Remoting Technology Projection Indigo can be found at [Mic04b] we also summarize some key concepts in Outlook for the next generation on page 235.

Figure 8.16. Photocontrolled 2-D MPS nanostructure of an ABA triblock copolymer on water and supposed aggregation state. Reprinted with permission from the American Chemical Society.

Here, NCurses typeahead is set for standard input, most likely to restore typeahead after being disabled.

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 #include <ncurses.h> int main(void) { initscr(); typeahead(-1);

essentially in a reversible manner (Fig. 8.17) (Kadota et al., 2006), although the morphological alternations are not suf cient because of the suppressed motional freedom on the solid surface.

/* Disable typeahead */





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This section explains some basics that should be understood in outline before reading on Just as Java, NET is based on a virtual machine architecture The virtual machine is called Common Language Runtime (CLR), also named runtime in this section The runtime runs programs written in NET assembler , the Microsoft Intermediate Language (MSIL) Many source languages can be compiled into MSIL, including C#, C++, VBNET, Eiffel Since everything is ultimately represented as MSIL, a great deal of language interoperability is possible For example, you can let a C++ class inherit from a C# class NET supports namespaces to avoid name clashes Just as in C++, a namespace is logically a prefix to a name Multiple classes can exist in the same namespace In contrast to Java, there is no relationship between namespaces and the file system location of a class.

addstr( All this text will be put to the screen without a\n ); addstr( keyboard interruption. ); refresh(); getch(); endwin(); return 0; }

Many efforts have been made to induce macroscopic alignment of the MPS patterns (Lazzari and De Rosa, 2006). When block copolymers with LC nature are

Sample output:

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Assemblies are completely independent of namespaces: assemblies are the packaging format, a kind of archive, for a number of NET artifacts, such as types, resources, and metadata (see below) The elements of a namespace can be scattered across several assemblies, and an assembly can contain elements from any number of namespaces So, namespaces are a means to structure names logically, whereas assemblies are used to combine things that should be deployed together It is of course good practice to establish some kind of relationship between namespaces and assemblies to avoid confusion, for example to put all the elements of one namespace into the same assembly NET provides many features that are known from scripting or interpreted languages For example, it provides reflection: it is possible to query an assembly for its contained artifacts, or to introspect a type to find out its attributes, operations, supertypes, and so on.

Refreshing takes place so quickly on x-terminals that you d really need to hook up a remote terminal, set it to something slow, and then test this function to really see the results.

200 nm (a) (b)

newterm(), flushinp(), intrflush()

200 nm (c)

unctrl()

It is also possible to create NET types and assemblies on the fly CodeDOM and the ReflectionEmit namespace provides facilities to define types, as well as their complete implementation..

The unctrl() function is used primarily to convert control codes to a displayable string using the ^c format, where ^ is the control prefix and c is a letter or symbol corresponding to the code.

Figure 8.17. Photoinduced modi cation of 2-D MPS nanostructures of the triblock copolymer monolayer on mica. (a) Initial cis-rich state, (b) trans-rich state after UV irradiation, and (c) successive cis-rich state after visible light irradiation.

char *unctrl(chtype c);

24.09.2004 21:03

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