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Scheme 12.3 Preparation of a PEO-based azo triblock copolymer by a modi ed ATRP method. Source: Reproduced from Yu et al., 2005c.

AsyncRequestor requestor = new AsyncRequestor(); requestor.invokeFireAndForget(endpointURL, operationName, null, rt);

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pseudostilbene, where the azo is usually substituted with electron donor and electron acceptor substituents. It is dif cult to directly synthesize BCs containing amino-azo or their push pull derivatives by ATRP because of the inhibition effect of the amino-azo-containing monomers toward free radicals (Wang et al., 2007). The PACR is a convenient way to introduce such azo groups into macromolecular chains, as shown by Wang et al. (1997a,b). Recently, they prepared amorphous azo BCs by the PACR of an amphiphilic PEO-based precursor and then studied the photoinduced shape change of the spherical aggregates formed by the postfunctionalized azo BCs.

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To deal with the asynchrony patterns RESULT CALLBACK, POLL OBJECT, or SYNC WITH SERVER, the client asynchrony handler types ResultCallback, PollObject, and SyncWithServer are provided. These are instantiated by the client and handed over to the REQUESTOR. The asynchronous REQUESTOR handles the invocation with an AsyncInEach invocation handler runs in its own thread of control and deals with one invocation. A thread pool is used to improve performance and reduce resource consumption. The client asynchrony handlers are sinks that are responsible for holding or handling the result for clients.

New pad created...and now it s gone!

Scheme 12.4 Schematic illustration of the synthesis of well-de ned azo BCs by a polymer analog reaction.

Maybe someday one of your NCurses programs will find use for a pad or maybe even a subpad or two. They re handy structures to have, especially if you have a predefined chunk of information you d like brought into your windows from time to time.

The pechochar() function both places a character on the pad and displays it on the screen but only after a chunk of the screen has been squared off with prefresh(). Listing 11-6 shows a program that makes use of it.

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To make an asynchronous invocation, the client only has to instantiate the required client asynchrony handler (that is, a class implementing a

Upon supramolecular self-assembly, low molecular-weight additives can be used to adjust the properties of BC bulk lms by hydrogen bonds. Ikkala and coworkers rst introduced this concept in PS-b-poly(4-vinylpyridine) (P4VP) stoichiometrically complexed with pentadecylphenol molecules to form the supramolecules by hydrogen bonding (Makinen et al., 2000). The advantages of this method are as follows: 1. Selective hydrogen bonding between one of the blocks (P4VP) of BCs and the additive 2. Obvious microphase separation in bulk lms 3. Easy extraction of the additive by selective solvents

11

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 #include <ncurses.h> int main(void) { WINDOW *p; char text[] = This is interesting ; char *t; initscr(); /* create a new pad */ p = newpad(50,100); if( p == NULL ) { addstr( Unable to create new pad ); refresh(); endwin(); return(1); } t = text; prefresh(p,0,0,1,1,1,25); while(*t) pechochar(p,*t++); wgetch(p); endwin(); return 0; }

Scheme 12.5 Synthesis of azo BCs by a polymer analog reaction. Source: Reproduced with modi cations from Mao et al., 1997.

24.09.2004 21:09

The code makes use of prefresh() in line 22 to box off a chunk of the screen, only a line to display the text. The while loop then uses pechochar() to read a string of text that is both sent to the pad and also displayed on the screen. You should see:

Scheme 12.6 An amorphous azo BC prepared by PACR. Source: Reproduced with modi cations from Wang et al., 2007.

Know that you can use all the standard NCurses functions with a pad except the following: mvwin() scroll()

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subtype of AsyncHandler) and provide it to the REQUESTOR S operation invoke. This operation is defined as follows:

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