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L. Cabrera, G. Copeland, W. Cox, M. Feingold, T. Freund, J. Johnson, C. Kaler, J. Klein, D. Langworthy, A. Nadalin, D. Orchard, I. Robinson, J. Shewchuk, and T. Storey: Web Services Coordination (WS-Coordination), September 2003 http://www-106.ibm.com/developerworks/library/ws-coor/ E. Christensen, F. Curbera, G. Meredith, and S. Weerawarana: Web Services Description Language (WSDL) 1.1, 2001 http://www.w3.org/TR/wsdl G. Coulouris, J. Dollimore, and T. Kindberg: Distributed Systems Concepts and Design, Addison-Wesley, Reading, MA, 1994

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present a cost-effective solution, but the restricted azobenzene solubility, phase separation, and molecular aggregation due to pp stacking limit the loading level and the ef ciency, respectively With regard to mass transport, some authors explain poor SRG-forming properties of guest host materials with the argument that nontethered azobenzenes cannot transfer the translational motion to the matrix, and in this way, a migration of the polymer chain could not take place or is strongly restricted The widely accepted conclusion is that covalent bonding between the photoactive group and the inactive matrix polymer is required for ef cient induction process and stable SRG Therefore, a large variety of azobenzene-functionalized polymers with different chemical structure, molecular weight, glass transition temperature, and azobenzene content have been investigated (see Natansohn and Rochon, 2002; 4 of this book).

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Almost all of them undergo the photoorientation and light-driven mass transport; the ef ciency of the processes is being strongly affected by the above-mentioned parameters of the polymers Especially sidechain azobenzene-containing polymers have been shown as very effective materials for photoorientation and SRG formation Multistep syntheses are required to manufacture such functionalized polymers from commercially available chemicals, and consequently, they are expensive The exact control of polarity, molecular weight, glass transition temperature, and viscosity are rather dif cult in such polymers, and reproducibility is a problem The availability and variety of speci cally functionalized structures is strongly limited Moreover, the puri cation and the solubility of the polymers are dif cult problems Restricted solubility requires using environmentally nonfriendly organic solvents Therefore, a number of activities to develop alternatives to glassy functionalized polymers were pursued.

After this statement, the character at location 5,0 is removed, and all remaining text on that line is slid over to the left one notch.

[CCM+01]

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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 #include <ncurses.h> #define #define #define #define Y 5 X1 10 X2 60 DELAY 250

There are only few examples for the induction of permanent anisotropy in bulk lms of neat azobenzenes (Tanino et al, 2007; Ishow et al, 2006; Presnyakov et al, 2006; Shirota, 2005; Ando et al, 2003; Chigrinov et al, 2003, 2002; Nakano et al, 2002; Perschke and Fuhrmann, 2002; Stracke et al, 2000; Utsumi.

int main(void) { char text[] = Elvis found alive *** Stock market tops 20,000 ***; Rocky XII big box office hit *** Congressman indicted *** ; char *t; initscr(); noecho(); nodelay(stdscr,TRUE); t = text; while( getch() == ERR ) { if( *t == \0 ) t = text; mvinsch(Y,X2,*t); mvdelch(Y,X1); refresh(); napms(DELAY); t++; } endwin(); return 0; }

[CDK94]

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et al, 2000; Shirota et al, 1998; Klima and Waniek, 1957) If the crystallization can be suppressed, the induction of anisotropy is possible in lms of lowmolecular-weight azobenzene derivatives (Fig 22) Surprisingly, SRG formation in a single crystal of 4-(dimethylamino)azobenzene was reported (Nakano et al, 2002) Low-molecular-weight glass-forming systems are an alternative to functionalized polymers (Tanino et al, 2007; Ishow et al, 2006; Presnyakov et al, 2006; Shirota, 2005; Ando et al, 2003; Chigrinov et al, 2002, 2003; Nakano et al, 2002; Perschke and Fuhrmann, 2002; Stracke et al, 2000; Utsumi et al, 2000; Shirota et al, 1998; Klima and Waniek, 1957) Sterically hindered bulky azobenzenecontaining molecules are a new family of functionalized materials that form amorphous lms by spin coating and vacuum deposition without any dilution of the system.

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