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light of polymer nanoparticle complexes. A low concentration of photochrome (and low absorbances of samples) then becomes compatible with high magnitude of responses. High ef ciency at low absorbance opens the way to unexplored short response times in complex uids (high intensities of light can reach the bulk of samples). For instance, gels and colloid assemblies made photoswitchable on time scale of the order of diffusive times are expected to exhibit new nonequilibrium properties such as photocontrolled morphologies of precipitates (Klajn et al., 2007; Bell and Piech, 2006), or new sorting principles in analytical chemistry (Alcor et al., 2004). The length scale of stimulation can be focused down to micron size. All these features are of great potential bene t in microsystems and micro uidic applications to add a new route toward formation of gradients, modi cation of ow rates, etc. to the present devices based on local applications of heat or of electric eld. Finally, a second stage of ampli cation is recruited when the polymer complexes are close to a critical transition, including solubility, sol gel transition, or adsorption onto interfaces. Light can certainly be used to investigate the dynamics of such complex transitions. Practically, irradiation can be seen as a reversible target-selective tool that requires no extra additive to modify with short pulses of lights (shorter than characteristic diffusion times of the macromolecules) the properties of macromolecules and trigger the variation of interfacial properties (e.g., wettability), release/encapsulation or the continuous phase (e.g., when an emulsion swings between O/W and W/O). Study of the phototriggered dynamics and intermediate stages of phenomena becomes quite readily accessible with azocontaining polymer systems.

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A client invokes a remote operation on the REQUESTOR, which in turn creates a POLL OBJECT to be returned to the client immediately. As long as the remote invocation has not returned, the result available operation of the POLL OBJECT returns false. When the result becomes available, it is memorized in the POLL OBJECT. When it is next polled it returns true, and the client can fetch the result by calling the get result operation.

subwin()

Some results and conclusions presented are the outcome of several years of fruitful collaborations with C. Prata (synthesis of azo derivatives), G. Pouliquen, J. Ruchmann and I. Porcar (physical-chemistry investigations on association with proteins or surfactants), and S. Khoukh and P. Perrin (development of photoemulsi ers).

WINDOW *subwin(WINDOW *orig, int nlines, int ncols, int begin_y, int begin_x);

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Alcor D, Croquette V, Jullien L, Lemarchand A. 2004. Stochastic resonance to control diffusive motion in chemistry. Proc Natl Acad Sci USA 101:8276 8280. Alonso M, Reboto V, Guiscardo L, Mate V, Rodriguez Cabello JC. 2001. Novel photoresponsive p phenylazobenzene derivative of an elastin like polymer with en hanced control of azobenzene content and without pH sensitiveness. Macromolecules 34(23):8072 8077. Bell NS, Piech M. 2006. Photophysical effects between spirobenzopyran methyl methacry late functionalized colloidal particles Langmuir 22:1420 1427.

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orig is a window on the screen, which becomes the parent window of the subwindow. nlines and ncols are int values indicating the number of rows and columns the subwindow contains, respectively. Values range from 1 to the distance between the window s origin and the bottom and right edges of the window, respectively. When either nlines or ncols is 0, the subwindow extends from its origin to the bottom or right edge of the parent window, respectively. Neither nlines nor ncols can be negative. begin_y and begin_x give the subwindow s origin, the upper-right coordinate relative to the standard screen. Values for begin_y and begin_x are ints, ranging from 0, 0 (the upper-left corner of the screen) to the maximum number of rows and columns for the standard screen. (See COLS and LINES.)

E E E The POLL OBJECT has to provide at least two operations: one to check whether the result is available, the other to actually return the result to the calling client. Besides this client interface, an operation for storing the result received from the server is needed. Most POLL OBJECT implementations also provide a blocking operation that allows clients to wait for the availability of the result if they choose to do so. The core idea of this pattern follows the Futures concept described in [Lea99], but POLL OBJECT extends it to distributed settings and allows the availability of the result to be queried in a non-blocking fashion whereas with Futures this query would block. typically depend on the interface of the remote object. That is, the client requires a POLL OBJECT that offers the out parameters and return values of the remote object s operations. There are three options in the design of POLL OBJECTS:

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