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chiral azobenzene compounds were synthesized by introducing different chiral groups into the same azobenzene group via ester bond without any spacers (Fig. 10.7). HTPs of some chiral compounds without azobenzene group are given in Table 10.2. It is noteworthy that HTP is increased by the introduction of the azobenzene group into the chiral compounds. This may be due to the enhancement of the intermolecular interaction between chiral molecule and LC molecule by the introduction of the azobenzene group with the rod shape. The molecular long axis and molecular aspect ratio are increased by the introduction of the azobenzene group. The molecular length (L) and diameter (D) estimated from the models obtained by MOPAC/PM3 method are given in Table 10.1. The molecular aspect ratio (L/D), which is de ned as the ratio of the molecular length to the molecular diameter of chiral azobenzene molecules, is a measure of anisotropy of the molecular shapes. The anisotropy in the molecular shape is one of the important parameters for appearance of LC phases (Onsager, 1949). In other words, the molecular aspect ratio is related to the anisotropic intermolecular interaction between the chiral and the LC molecules. Therefore, the higher the molecular aspect ratio becomes, the higher HTP of the chiral compounds becomes. Figure 10.9 shows the snapshot after 100 ps of mixture of 5CB/p-azo-9 (98/ 2 mol%) obtained by MD simulation. It seems likely that p p stacking interaction between 5CB molecules is enhanced through the intermolecular interaction between the chiral azobenzene molecule and 5CB molecule. As a result, the order parameter, S, was increased by mixing trans-p-azo-9 in 5CB. However, S of 5CB mixed with cis-p-azo-9 was almost constant. The molecular orientation of the LC molecules doped with the trans-azobenzene is stable relatively to that doped with



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The row and column come first, and the character to punch in that spot goes last. Again, this is just like combining the two functions, move() and addch().

TA B L E 1 0 . 1 . HTPs [( 108 m 1 mol 1 g-E44), Experimental], the Length of the Long Axis, L, and the Diameter, D [(A), Measured from Molecular Orbital Calculation with PM3 Method], Data of Chiral Azobenzene Compounds





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The interesting thing about the transparent proxy is that you never really see its implementation code. There is no explicit code generation step involved here. While in CORBA, for example, you have to manually code-generate the CLIENT PROXY, this is not necessary in .NET. .NET Remoting takes advantage of the features provided by the .NET runtime which transparently generates the proxy on the fly. Let s look at this a little bit more closely. If a client wants to communicate with a remote object, typically it uses the Activator.GetObject operation to obtain a reference. This operation returns a CLIENT PROXY for the requested remote object, optionally contacting the server application to physically create the instance (depending on the activation mode). The client specifies two parameters: the type of the remote object (as an instance of the Type type) as well as a URL that points to the required object. Since the client passes the type object to the operation, this approach requires the remote object type to be available on the client already. There is thus no need to transfer the interface to the client as part of the Activator.GetObject call. The returned transparent proxy implements the interface of the remote object by forwarding each method invocation to the real proxy that is

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