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Azo BCs are multifunctional polymeric materials, which combine the photochemical properties of azo polymers and the microphase separation of functional BCs. On the one hand, the azo block and the other segments cannot be miscible, unlike statistically random copolymers in which the azo moieties are dispersed homogeneously over the whole bulk lms. On the other hand, the azo BCs cannot form macroscopically phase-separated structures like polymer blends (Bates and Fredrichson, 1999). The azo moiety may play the roles of both mesogen and photosensitive chromophore, when it is attached to the polymer main chain by a longer soft spacer. Both the photoisomerization and the phase transition of the LC to the isotropic phase are involved in the process of microphase separation because of



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AsyncRequestor requestor = new AsyncRequestor(); PollObject p = (PollObject) new SimplePollObject(); requestor.invoke(p, null, endpointURL, operationName, null, rt); while (!p.resultArrived()) { // do some other task ... } System.out.println("Poll Object Result Arrived = " + p.getResult());

Scheme 12.8 Preparation of azo BCs by using living cationic polymerization and free-radical polymerization techniques. Source: Reproduced from Serhatli and Serhatli, 1998.

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the immiscibility between the azo blocks and non-azo blocks. As shown in Fig. 12.2, all the processes in the microphase separation at different temperatures might be in uenced by the azo photoisomerization, andthe microphase-separated nanostructures in azo BC lms could have effect on the photochemical behavior of azo blocks and vice versa (Cui et al., 2003). The photochemical control and supramolecular self-assembly make the azo BCs in solid state superior to that of azo homopolymers or azo random copolymers. On the one hand, the azo BCs inherit most of the excellent properties of azo homopolymers (Ichimura, 2000), such as trans cis photoisomerization, photoselective alignment with azo transition moments almost perpendicular to the polarization direction of the actinic light, and photochemical phase transition, since the trans-azo can be a mesogen because its molecular shape is rodlike, whereas the cis-azo never shows any LC phase because of its bent shape. All the illustrations of the photosensitive performances are shown in Fig. 12.3 (Yu et al., 2005a).

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The class SimplePollObject implements the PollObject interface. Here the clientACT parameter is set to null because we can use the object reference in p to obtain the correct POLL OBJECT. More complex AsyncHandlers that handle multiple replies use the clientACT to identify the request belonging to a reply.

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Supramolecular self-assembly in azo BC films Azo BC in isotropic melt Order disorder transition Microphase separation Temperature T > TLC Rubbery or LC T > Tg Vis, trans Glassy, crystal, or LC Glassy or LC UV Rubbery or LC T > Tg T > Tm

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the respective AsyncHandler has to be used. For example, the following code instantiates a RESULT CALLBACK and then sends ten invocations, each handled by the same RESULT CALLBACK object. Each invocation

Figure 12.2. Microphase separation and azo photoisomerization in bulk lms of well-de ned azo BCs. TLC is LC isotropic phase transition temperature.

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In NCurses, soft labels are visual elements only. There is no back connection between function keys and soft labels, unless you program one yourself. Otherwise, setting and displaying soft keys is merely a visual part of NCurses.

Figure 12.3. Properties of azo BCs inherited from azo homopolymers. A is the absorption of azo chromophores, y represents the angle between the polarization direction of the linearly polarized light and the transition moment of an azo moiety.

24.09.2004 21:09

If you re writing a program that uses soft labels, you ll need to use the slk_init() function:

slk_init(n)

On the other hand, the well-de ned azo BCs show excellent features different from azo random copolymers Recently, the performance of molecular cooperative motion (MCM) between azo moieties and other photoinert groups has been studied in azo triblock copolymers with speci cally designed structures (Yu et al, 2007) Triggered by a linearly polarized laser beam at 488 nm, the azo chromophores became aligned by the Weigert effect, then the photoinert groups were oriented together with the azo moieties under the function of MCM, although they do not absorb the actinic light (Wu et al, 1998a,b) When the azo and the photoinert mesogens form the majority phase (continuous matrix), the photocontrol orientation can be transferred to the microphase-separated nanodomains inside the LC matrix owing to SMCM (see Fig 124; Yu et al, 2005c).

All soft label functions begin with slk. I assume that slk stands for soft label keys, though that s just a guess. The slk_init() function must appear before the initscr() function in your code. The reason is that slk_init() changes the size of the standard screen, reserving the bottom row for the soft keys. All NCurses commands, then, affect only the top several rows of the screen; the bottom row is reserved and cannot be touched, other than to mess with the soft labels.

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