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Photoorientation concerns closeorder motion of azobenzene chromophore (rotation), whereas the formation of SRG involves long-distance movement (mass transport) of chromophores and, possibly, of nonphotoactive polymer chains According to Zucolotto et al (2003), the electrostatic interactions between active and inert layers serve as a mean for the SRG formation but, on the contrary, tend to hinder the photoisomerization of azobenzenes This inherent con ict together with restriction of molecules freedom by layered structure explains rather ineffective SRG inscription in LbL architectures The materials used for recording of SRG were similar and are depicted in the Figs 27 and 28 Between them, three azodyes, Direct Red 80, Congo Red, and Brilliant Yellow (Fig 27), were employed For PDADMAC/(Congo Red) structures (He et al, 2000), the dependence of SRG ef ciency on the number of layers was investigated.



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Maximum relief height of 140 nm at corresponding rstorder DE of 17% has been achieved for 2-mm thick lm consisting of 640 layers This is actually the highest value reported so far for LbL layers Dependence of the achieved relief height on the number of bilayers is shown in Fig 213 As the lm thickness is of comparable value, used generally for polymer materials, low ef ciency cannot be attributed to layer thickness Also, writing kinetics for thick layers was rather slow at the irradiation intensity of 150 mW/cm2, the maximum of rst-order DE was achieved in 75 min..

The clear() function clears the screen or named window, writing blanks, or space characters, to every screen position.

Microsoft: Information on Microsoft COM+ technologies, 2004 http://www.microsoft.com/com/tech/COMPlus.asp

int erase(void); int werase(WINDOW *win);





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Figure 2.13. Dependence of surface modulation amplitude (according to AFM measurements) on the number of deposited bilayers in PDADMAC/(Congo Red) LbL lms. Source: He et al., 2000. Reprinted with permission from American Chemical Society.

The erase() function has no arguments. It s a pseudo function that affects only the standard screen. Refer to the w prefix entry later in this appendix for information on the win argument.

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You don t see the window erased until a call to refresh() updates the window. Clearing the screen also homes the cursor; after the erase() function, the cursor is placed at location 0, 0. The erase() function removes only characters and their attributes. It does not affect the background character and its attributes. If a background character is set via bkgd() or bkgdset(), then that character will show up in the blanks erase() fills the screen with. erase() is the same as werase(stdscr). The erase() function is visually the same as the clear() function; however, clear() also calls the clearok() function to enforce the erasure and redisplay of the screen. Because of the overhead involved with clear(), erase() is the quicker of the two functions, though on many terminals the speed difference is negligible.

The authors mentioned two differences in behavior in contrast to azobenzenecontaining polymers, namely, bleaching during SRG inscription (azodyes, in particular Congo Red, were photochemically not so stable as azobenzene-containing polymers) and recording ef ciency independence on polarization con guration of the writing beams. The authors mention here well-known (Brown, 1971) property of azobenzene derivatives with OH or NH2 group in ortho-position. The photochemistry of such derivatives is dominated by phototautomerization through proton transfer, leading to bleaching. Very thin LbL lms of (Direct Red 80)/PDADMAC consisting of 20 layers exhibited only 5-nm deep SRG and that required 3-h exposure (Kaneko et al., 2002; Shinbo et al., 2002). Generally one cannot expect much higher modulation depth in the lms of 15-nm thickness. Otherwise, when thick lms consisting of 600 layers of Brilliant Yellow alternated with either PDAMAC or PAH were used (Zucolotto et al., 2003), higher amplitude of 120 nm has been achieved after 1-h exposure. It may be adverted here for comparison to the formation of the ionic complex using the same azodye (Brilliant Yellow), discussed later in more detail, where SRGs with DE of 15% have been inscribed at the comparable conditions (Stumpe et al.,

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