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Recently, construction of 2-D and 3-D periodic structures from monodispersed colloidal spheres has aroused tremendous research enthusiasm for their selfassembled architecture and fascinating applications (Xia et al., 2000). The colloidal crystals can be obtained by methods such as transferring the colloidal array formed at the air liquid interface, exploiting the capillary forces to drive the assembly, and using electrophoretic deposition or sedimentation in a force eld (see, e.g., Cheng et al., 1999; Jiang et al., 1999a; Park and Xia, 1999; Dimitrov and Nagayama, 1996). The colloidal spheres discussed in the preceding sections can be used as a new type of the building block to construct colloidal crystal through selfassembling methods.

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1 2 3 4 5 6 7 #include <ncurses.h> #define CENTER 1 #define LCOUNT 8 int main(void) {

8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33

The client interacts with the CLIENT PROXY, which supports the same interface as the remote object. The CLIENT PROXY uses the REQUESTOR, as part of the distributed object middleware, to construct and send the remote invocation.

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One of the most interesting photoresponsive properties of azo polymers is the photoinduced birefringence and dichroism (Xie et al., 1993). The photoinduced anisotropy is caused by the disparity of the repeated trans cis isomerization of azo chromophores under linear polarized light irradiation. The most ef cient excitation occurs in the polarization direction, which can force the chromophores to continually change their orientation and to be eventually stabilized at the direction perpendicular to the polarization (Natansohn and Rochon, 2002). The effect shows potential applications in areas such as reversible optical data storage, optical switching and sensors. The colloids composed of azo polymers can be a new type of the colloid-based material that exhibits the photoinduced birefringence and dichroism (Li et al., 2005a). Figure 5.20 shows the chemical structure of an azo polymer (PNANT) that has been prepared for the purpose. PNANT contains both pseudostilbenetype azo chromophores and ionizable carboxyl groups in the side chain in a random sequence. PNANT was synthesized from a PAC sample with the average degree of polymerization (DP) of 239 and a polydispersity index of 1.53. The precursor polymer containing anilino moieties was synthesized by the reaction between a proper amount of N-ethyl-N-(2-hydroxyethyl)aniline and PAC through the Schotten Baumann reaction. Unreacted acyl chloride groups were then hydrolyzed to obtain the COOH groups after the reaction. Finally, PNANT was obtained by azo coupling reaction between the precursor polymer and diazonium salt of 4-nitroaniline. In this reaction, the molar ratio of the diazonium salt to the anilino moieties of the precursor polymer was 1.1 in order that the anilino moieties were completely reacted. The details of these reactions can be seen in Li et al. (2005a), Wu et al. (2001), and Wang et al. (1997b). The average DF,

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char labels[LCOUNT][9] = { Help! , File , Print , Text , Edit , Quick , Conf , System }; int x; slk_init(0); initscr(); for(x=0;x<LCOUNT;x++) slk_set(x+1,labels[x],CENTER); slk_refresh(); addstr( Press Enter to hide the soft label keys:\n ); refresh(); getch(); slk_clear(); addstr( Press Enter to restore the soft label keys:\n ); refresh(); getch(); slk_restore(); getch(); endwin(); return 0; }

Sample output: Soft keys are displayed (refer to the figure for slk_set()).

Figure 7.8. Schematic representation of the formation of a physical gel by transient associations with nanoparticles in semidilute solutions of polymer and the corresponding rheological signature. The elastic (Gu) and loss (Guu) moduli are plotted as a function of the frequency of the oscillating strain for samples containing the same polymer concentration (1 wt%) and bovine serum albumin at 0, 0.03, and 0.2 g/L, respectively.

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