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Brinker and coworkers prepared TSUA-modi ed mesoporous silica particles using the aerosol-assisted self-assembly route and demonstrated photocontrolled release of dye molecules from the nanocomposite particles (Liu, 2004). A dye molecule, oil blue N (OBN), was used to probe the effective pore size change of the azobenzene-modi ed nanocomposite particles in response to light stimuli. Uptake of OBN molecules into the pores of the particles was carried out by stirring the suspended particles in an OBN EtOH solution (5 mmol/L) for 48 h under UV irradiation. As described previously, the UV irradiation causes trans-cis isomerization of the azobenzene ligands located on the pore surfaces of the nanocomposite material, and correspondingly, an enlargement of the effective pore size because of the shorter effective molecular chain length of the azobenzene ligands in the cis conformation. In this case, the pores were lled completely. After the uptake process, the particles were centrifuged, washed with ethanol (in the dark) to remove the OBN molecules adsorbed on the particle surface, and dried in a vacuum. In the release process, the dye- lled particles were dispersed in 5 mL EtOH. One sample was stirred under UV light irradiation and the other was stirred in the dark. After ltration, the concentration of the OBN molecules released into EtOH was determined by the absorbance (A) of the solution at lmax (644 nm) using UV/visible spectroscopy. The release data of the two samples are shown in Fig. 13.20. There are two factors in uencing the release rate: the effective pore size



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End-to-end priority preservation In order to enable end-to-end preservation of QoS, priorities need to be mapped between various operating systems, as every operating system defines its own range of priorities. For example, when invocations of a client running on VxWorks in a thread with a certain priority are invoked on a server running LynxOS, the priority of the dispatching and executing thread should be aligned with that client priority. The way in which priorities are handled end-to-end follows two different models.

The box() function draws a simple box around the outside edges of a window. The function uses the ACS characters to draw the box, though the characters used to draw the horizontal and vertical lines can be specified inside the box() function.

0.03 0 5 10 15 20 25 Time (hour)

int box(WINDOW *win, chtype verch, chtype horch);

24.09.2004 21:13





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win refers to a specific window or stdscr for the standard screen. verch is a chtype character used to create the left and right (vertical) lines of the box. The chtype combines both a character and an attribute, though

Figure 13.20. Release of the dye molecules from the azobenzene-modi ed nanocomposite particles under UV exposure and in the dark.

typically only a character (constant or variable) is used. See Appendix C for more information on chtypes. horch is a chtype character used to create the top and bottom (horizontal) lines of the box. When zero is specified for either verch or horch the default ACS character is used: ACS_VLINE for verch and ACS_HLINE for horch. See Appendix B for more information on these characters.

The characters used to draw the corners of the box are shown in Table A-2. The box() function is equivalent to the following border() function:

A client-propagated model. The client thread s priority gets sent to the server using the INVOCATION CONTEXT, as illustrated in the figure below.

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and the difference of the concentration of the probe molecules (OBN) between the nanocomposite particles and the EtOH solution In comparison to the nanocomposite particles in the dark, the release rate of the nanocomposite particles under UV light irradiation is faster when to5 h because of the larger effective pore size As we know, the total amounts of OBN molecules taken into the nanocomposite particles in the two samples are the same With time, the difference in concentration of the OBN molecules between the nanocomposite particles and the EtOH solution under UV light irradiation is less than that in the dark, thereby decreasing the release rate In the dark at tE11 h, the concentration of OBN molecules in EtOH solution levels off, indicating a complete release of OBN molecules from the nanocomposite particles.

wborder(win,verch,verch,horch,horch,0,0,0,0)

There is no wbox() function. Also refer to the Notes for border() as the same information applies to both functions.

Under UV light irradiation, the absorbance reaches the plateau value of the complete release in the dark at t = 6 h and decreases thereafter The decrease in the absorbance occurs because the UV light irradiation bleaches the OBN dye molecules, as demonstrated by a control experiment The absorbance at 644 nm of OBN in ethanol solution under UV light irradiation decreases gradually at the beginning and decreases dramatically after tW5 h A simple model was developed to evaluate the effective diffusivity of OBN in the photoresponsive nanocomposite particles In this model, it was assumed that the particles had uniform size and each particle was surrounded symmetrically by an equal volume of solution (volume of solution/number of particles) Although the particles had a wide size distribution, it is reasonable to use the average particle size to evaluate the effective diffusivity.

A server-declared model. The priority is set in the POA and sent to clients as part of the ABSOLUTE OBJECT REFERENCE. The following figure illustrates this.

box(stdscr,0,0);

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