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In applying QCA, the pair distribution function of particle positions must be specified. The Percus-Yevick approximation is used in calculating the particle distribution functions in the study.



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Pair Distribution Functions of Multiple Sizes For the Percus-Yevick approximation in the case of general multiple species, the solution is obtained by Baxter [1970] and given in 8 of Volume II. The pair distribution functions are calculated by assuming that the particles are non-penetrable spheres without interparticle force. The total correlation function h ij (r) is defined as (6.4.60) where r = hij(r).

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Pair Distribution Functions of Sticky Particles In natural media, the densely packed particles can have adhesive force. They adhere together to form aggregates. Thus the model of sticky particles was developed. The sticky particle has a stickiness parameter T. The smaller the T is, the more sticky the particles are. The Percus-Yevick approximation of the pair distribution function g( r) for the sticky spherical particles can be solved analytically using the factorization method of Baxter [1970]. The calculations of g(r) can be found in 8 of Volume II. We will study the use of dense media with a single particle size a and with a sticky parameter Sticky parameter T. In Fig. 6.4.2, the pair functions for several T'S are plotted. The scattering depends on the structure factor H(p). In Fig. 6.4.3, the structure factor H(p) is plotted as a function of pb, where b = 2a is the diameter of the particles, for several T'S. For non-small T, the interparticle force is small. H(O) is negative indicating that scattering is smaller than independent scattering. For small T, H(O) is positive indicating that scattering is larger than independent scattering. We note in Fig. 6.4.3 that for sticky particles, there are sharp variations of pair functions. These make it difficult to usp the Lorentz-Lorenz law to calculate ImK which is much smaller than ReK. Thus, in implementations, we use Lorentz-Lorenz law to calculate ReI< but use (6.4.41) to calculate "".. and (6.4.15) to calculate ""a' Then 21mI< = ""a + K'8'

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