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400 450 500 Wavelength (nm)

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Figure 13.25. Photo and thermal isomerization of azobenzene ligands in the photoresponsive aerogel. (a) As-prepared, (b) after UV irradiation of sample (a) for 40 min, (c) after room light exposure of sample (b) for 60 min, (d) after heating sample (b) to 1001C for 10 min.





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In this section we provide a brief overview of patterns and pattern languages that are directly related to patterns in this book Patterns for networking and concurrency Distributed object middleware follows two architectural patterns documented in POSA1 [BMR+96]: Broker, in terms of mediating object invocations between communication participants, and Layers, regarding the separation of responsibilities such as connection handling, marshaling, decomposition, and dispatching of invocations Distributed object middleware operates on top of network protocols, such as TCP/ IP It does not reinvent the wheel for this, but handles network connections and the inherent concurrency of networked communication using existing implementations and concepts A number of patterns for networking and concurrency are documented in the following literature: POSA2 [SSRB00] contains many patterns that are used to implement distributed systems The book describes many patterns that are relevant when applying the patterns in this pattern language.

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cis conformation in the as-prepared lm. Using a molar absorption coef cient (e) of 2.59 104 M 1 cm 1 for the trans isomer of TSUA, the concentration of the trans isomer in the lm was estimated to be 0.27, 0.22, 0.20, and 0.17 M for lm samples in Fig. 13.25d, a, c and b, respectively. It is dif cult to estimate the concentration of the cis isomer in the lm because the e value of the n p* transition of the cis isomer is unknown. It is reasonable that a portion of the azobenzene ligands are in the cis conformation because the gel shrinkage during the lm formation process caused by ethanol evaporation leads to a portion of the azobenzene ligands adopting the cis conformation with shorter molecular length. Only upon powerful stimulation (heat) to overcome the force (B200 pN/ azobenzene ligand [Hugel et al., 2002]) involved in the conformational change does the cis isomer change to the trans isomer that has a longer molecular length. 13.4.2.3. Stress Development and Relaxation of Azobenzene-Modi ed Polysilsesquioxane Gels. The dimensional change associated with the trans 2cis isomerization of the azobenzene ligands contained in the polysilsesquioxane gel lms causes the gel network to shrink or expand in response to light stimuli, which involves stress development and relaxation of the lm. Brinker and coworkers used a homemade beam bending setup to observe the stress behavior in response to UV light irradiation. The in-plane stress during alternating UV light exposure and dark exposure is calculated from Stoney s equation as follows: s Es ds2 d Vs df

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For example to implement CLIENT REQUEST HANDLERS and SERVER REQUEST HANDLERS, the following patterns should be considered: Reactor, Half-sync/Half-async, Leader/Followers, Monitor Object, and Active Object Doug Lea s book Concurrent Programming in Java Design Principles and Patterns [Lea99] describes several concurrency patterns with a special focus on Java Guarded Suspension serializes access to shared objects whose methods can only be executed when certain conditions hold true: the pattern can be used to serialize access to remote objects and other resources that are concurrently accessed The Future pattern provides a generalized form of POLL OBJECT: it provides a Proxy that can be used to query for results that are computed asynchronously The patterns in the paper A System of Patterns for Concurrent Request Processing Servers [GT03] documents several patterns for concurrent request handling in high-performance servers.

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