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Photomobile polymer materials towards light driven plastic motors Angew Chem Int Ed Engl 47:4986 4988 Yoshida R, Uchida K, Kaneko Y, Sakai K, Kikuchi A, Sakuraui Y, Okano T 1995 Comb type grafted hydrogels with rapid de swelling response to temperature changes Nature 374:240 242 Yu Y, Nakano M, Ikeda T 2003 Directed bending of a polymer lm by light Nature 425:145 Yu Y, Nakano M, Ikeda T 2004a Photoinduced bending and unbending behavior of liquid crystalline gels and elastomers Pure Appl Chem 76:1435 1445 Yu Y, Nakano M, Shishido A, Shiono T, Ikeda T 2004b Effect of cross linking density on photoinduced bending behavior of oriented liquid crystalline network lms containing azobenzene Chem Mater 16:1637 1643 Yu Y, Maeda T, Mamiya J, Ikeda T 2007 Photomechanical effects of ferroelectric liquid crystalline elastomers containing azobenzene chromophores Angew Chem Int Ed Engl 46:881 883..



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getch()

nocbreak()





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Yusuf Y, Sumisaki Y, Kai S. 2003. Birefringence measurement of liquid single crystal elastomer swollen with low molecular weight liquid crystal. Chem Phys Lett 382:198 202. Yusuf Y, Cladis PE, Brand HR, Finkelmann H, Kai S. 2004a. Hystereses of volume changes in liquid single crystal elastomers swollen with low molecular weight liquid crystal. Chem Phys Lett 389:443 448. Yusuf Y, Ono Y, Sumisaki Y, Cladis PE, Brand HR, Finkelmann H, Kai S. 2004b. Swelling dynamics of liquid crystal elastomers swollen with low molecular weight liquid crystals. Phys Rev E 69:021710. Yusuf Y, Huh JH, Cladis PE, Brand HR, Finkelmann H, Kai S. 2005. Low voltage driven electromechanical effects of swollen liquid crystal elastomers. Phy Rev E 71:061702. Zanna JJ, Stein P, Marty JD, Mauzac M, Martinoty P. 2002. In uence of molecular parameters on the elastic and viscoelastic properties of side chain liquid crystalline elastomers. Macromolecules 35:5459 5465. Zentel R. 1986. Shape variation of cross linked liquid crystalline polymers by electric elds. Liq Cryst 1:589 592. Zentel R. 1989. Liquid crystalline elastomers. Adv Mater 10:321 329. Zentel R, Reckert G. 1986. Liquid crystalline elastomers based on liquid crystalline side group, main chain and combined polymers. Makromol Chem 187:1915 1926. Zentel R, Benalia M. 1987. Stress induced orientation in lightly crosslinked liquid crystal line side group polymers. Makromol Chem 188:665 674. Zhang X, Li Y, Hu Z, Litter CL. 1995. Bending of N isopropylacrylamide gel under the in uence of infrared light. J Chem Phys 102:551 555. Zhang Y, Iijima S. 1999. Elastic response of carbon nanotube bundles to visible light. Phys Rev Lett 82:3472 3475. Zriny M, Feher J, Filipcsei G. 2000. Novel gel actuator containing TiO2 particles operated under static electric eld. Macromolecules 33:5751 5753.

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In the following examples, we also assume that there is only one INVOKER in the system. This manages a set of LIFECYCLE MANAGERS that implement different activation strategies.

See cbreak().

nodelay()

In 1995, a surprising and unprecedented optical effect was discovered in polymer thin lms containing the azo chromophore Disperse Red 1 (DR1), shown in Fig. 4.1. The Natansohn/Rochon (Rochon et al., 1995) research team and the Tripathy/Kumar collaboration (Kim et al., 1995b) simultaneously and independently discovered a large-scale surface mass transport when the lms were irradiated with a light interference pattern. In a typical experiment, two coherent laser beams, with a wavelength in the azo absorption band, are intersected at the sample surface (Fig. 4.2a, b). The sample usually consists of a thin spin-cast lm (10 1000 nm) of an amorphous azopolymer on a transparent substrate. The sinusoidal light interference pattern at the sample surface leads to a sinusoidal surface patterning, that is, a surface relief grating (SRG). These gratings were found to be extremely large, up to hundreds of nanometers, as con rmed by atomic force microscopy (AFM) (Fig. 4.3). The SRGs diffract very ef ciently, and in retrospect it is clear that many reports of large diffraction ef ciency before 1995, attributed to birefringence, were in fact due to surface gratings. The process occurs readily at room temperature [well below the glass-to-rubber transition temperature (Tg) of the amorphous polymers used] with moderate irradiation (1 100 mW/cm2) over seconds to minutes. The phenomenon is a reversible mass transport, not irreversible material ablation, since a at lm with the original thickness is recovered upon heating above Tg. Critically, it requires the presence and isomerization of azobenzene chromophores. Other absorbing but nonisomerizing chromophores do not produce SRGs. Many other systems can exhibit optical surface patterning (Yamaki et al., 2000), but the

Normally the getch() function waits for a key to be pressed. Waiting, waiting. nodelay() turns off the delay for a window, causing wgetch() to return ERR when a character isn t waiting or the character s value when a key has been pressed and its character is waiting in the input queue.

id := getObjectID() pc := getLifecycleManager(id)

int nodelay(WINDOW *win, bool bf);

Smart Light Responsive Materials. Edited by Yue Zhao and Tomiki Ikeda Copyright r 2009 John Wiley & Sons, Inc.

win is the name of a window. Only wgetch() commands referencing win (or getch() for stdscr) are affected by nodelay().

ro := invocationArrived(id) someOperation(x) invocationDone(ro)

N(CH2CH3)

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