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Using an average particle diameter of 2 mm and a Ds (diffusion coef cient of OBN in solution) value of 10 9 m2 s 1, the effective diffusion coef cients in the dark.

This function draws a box around the standard screen window using the default line drawing characters.

box(table1, * , * );

In the following code example we register a CORBA object with the POA for the client-propagated model. Operations are invoked with the



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Azo polymers have been shown to be excellent NLO materials (Yesodha et al., 2004; Delaire and Nakatani, 2000; Dalton et al., 1995; Burland et al., 1994). In azo systems, one has the additional advantage of using light to affect the chromophores. Although photoalignment orients the chromophore axis, it does not select out a preferred direction for the molecular dipole (thus, an equal number of dipoles point left and right ). In fact, evidence suggests that dipoles in these systems tend to orient antiparallel (H-aggregates) (Meng et al., 1996; Brown et al., 1995), thereby canceling polar order. Nevertheless, the photoalignment can be used to facilitate the electric poling, enabling it to be performed at room temperature and with a small DC eld (Jiang et al., 1996; Sekkat et al., 1995a; Blanchard and Mitchell, 1993a,b). Furthermore, by using polarized light and its harmonic, a net noncentrosymmetry can be obtained in an all-optical process (Zhong et al., 2001; Nunzi et al., 1998). This occurs because the mixture of a primary beam and its second harmonic creates a directional electric eld in the material. Another interesting approach for NLO uses dendrons ( half-dendrimers ) with azo functionalities (Yokoyama et al., 2000). The dendritic architecture forces all the chromophores within the dendron to align, which strongly enhances the NLO response. The dendron had a rst-order molecular hyperpolarizability 20 times larger than the monomer. With regard to applications, the azos have been shown to function as electro-optical switches (Yamane et al., 1999) and exhibit photorefraction (Iftime et al., 2002; Steenwinckel et al., 2001; Barrett et al., 1998; Ho et al., 1996), an NLO effect where photoconductivity permits light to establish a space charge grating, whose associated index grating refracts a probe light beam.





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This function draws a box around the window table1, using asterisks for both the horizontal and vertical lines.

Table A-2: ACS line drawing characters used in box() POSITION Top left Top right ACS CHARACTER ACS_ULCORNER ACS_URCORNER POSITION Bottom left Bottom right ACS CHARACTER ACS_LLCORNER ACS_LRCORNER

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The orientation and reorientation of LC domains has already been outlined. The azo chromophores act as mesogens and their photoalignment becomes transferred to the LC host. A very small azo content (a few mol% [Ikeda et al., 1990]) can lead to orientational control of LC domains. This is an excellent example of ampli cation of the azomolecular motion. The phase of a liquid crystal can also be switched with light. Irradiation produces cis isomers, which are poor mesogens and destabilize the nematic phase, thereby inducing a phase transition to the isotropic state. There are comparatively few examples of phototriggered increases in LC ordering. In one case, a nanoscale phase separation of the cis isomers led to a net increase in the order parameter of the LC phase (Prasad and Nair, 2001). In another system, a chiral azo was found to induce a cholesteric phase when it was in the cis state (Ruslim and Ichimura, 2001). With LC (Nikolova et al., 1997) or preoriented amorphous samples (Ivanov et al., 2000), one can photoinduce a chiral domain structure. Incident circularly polarized light becomes elliptically polarized because of the rst oriented layer. This ellipse subsequently reorients deeper chromophores, which in turn modify the ellipticity of the light. This reorientation continues throughout the lm depth. Overall, a chiral ordering of the chromophore domains is established (Nikolova et al., 2000). Remarkably, one can switch between a right- and left-handed

24.09.2004 21:13

1 2 3 4 5 6 7 8 9 10 11 12 13 14 #include <ncurses.h> int main(void) { initscr(); box(stdscr,0,0); mvaddstr(1,1, Ta-da! ); refresh(); getch(); endwin(); return 0; }

Sample output: The program draws a box around the entire screen, placing the words Ta-da! inside the box at row 1, column 1.

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