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Figure 6.2. Examples of amphiphilic block copolymers synthesized by atom transfer radical polymerization (ATRP) and reversible addition fragmentation chain transfer (RAFT) polymerization (end groups and block-linking groups are omitted).

The timeout delay has been set to 1000 milliseconds. Try to type in your name fast enough:

25.09.2004 21:11

Try to type quickly; if you pause longer than 1 second, either at first or between any keys, the program is over.



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its hydrolysis is much easier than the ester groups linked to azobenzene moieties However, it was found that the reaction is not trivial Under the used conditions, with which PAzoMA was not affected by the hydrolysis reaction, a complete (100%) removal of tBA groups is not possible The hydrolysis of PtBA-bPAzoMA actually results in a hydrophilic block that is a random copolymer of tert-butyl acrylate and acrylic acid, P(tBA-co-AA) The obtained diblock copolymer P(tBA-co-AA)-b-PAzoMA can form core shell micelles and vesicles depending on the preparation conditions And the incomplete hydrolysis of PtBA, which weakens the hydrophilicity of the hydrophilic block, was believed to play an important role in the effective dissociation and reformation of the micellar aggregates upon UV and visible light exposures By means of ATRP, the hydrolysis of PtBA remains the general route to the use of PAA as the hydrophilic block.

getch(), nodelay(), halfdelay()





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Another example of azobenzene amphiphilic BCP whose hydrophilic block was prepared through two steps is also depicted in Fig 62 (structure c) (Qi et al, 2008), namely, quaternized poly(4-vinyl pyridine)-b-poly {6-[4-(4-ethoxyphenylazo)phenoxy]hexyl methacrylate} (QP4VP-b-PAzoMA) To obtain this BCP, chlorine-terminated poly(4-vinyl pyridine) (P4VP) was rst synthesized and then used to initiate the polymerization for PAzoMA The resulting diblock of P4VP-bPAzoMA was subjected to a quaternization reaction using bromoethane to obtain the amphiphilic BCP Other azobenzene amphiphilic BCPs prepared using ATRP whose hydrophilic block is not PEO were also reported (Ravi et al, 2005) We note that this chapter concerns only amphiphilic BCPs and does not cover the numerous works of azobenzene BCPs, including the early syntheses using other polymerization techniques, which was reviewed elsewhere (Zhao, 2007a).

until an acknowledgement from the SERVER REQUEST HANDLER is sent the invocation has not yet been dispatched to the remote object.

touchline()

The touchline() function marks one or more rows in a window as changed, which directs NCurses to update the row(s) on the next call to refresh().

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It is of obvious interest to explore the use of other polymerization techniques that, being more tolerant to the experimental conditions and monomers, can produce amphiphilic azobenzene BCPs with no need for post reactions Notably, Su et al have recently reported the synthesis of such an amphiphilic diblock copolymer with PAA as the hydrophilic block using reversible addition fragmentation transfer (RAFT) polymerization (structure d in Fig 62) (Su et al, 2007) Using RAFT, they prepared PAA capped with dithiobenzoate and used it as the macro-RAFT transfer agent to polymerize the hydrophobic azobenzene polymer successfully It can be expected that more amphiphilic azobenzene BCPs will be synthesized using the controlled radical polymerization techniques (ATRP and RAFT) because of their simplicity, versatility, and ef ciency..

Refer to the entry for touchwin() for an explanation. The same material applies for the touchline() function, though for touchline() only

Client someOp()

specific lines in a window are marked as changed, and therefore written to the screen upon the next refresh() call.

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