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TSUA and BSUA were synthesized using isocyanato amino coupling reactions (Fig. 13.1) and characterized using several methods, including elemental analysis, nuclear magnetic resonance (NMR) spectra, and Fourier transform infrared (FTIR) spectroscopy (Liu, 2004). For the synthesis of TSUA compound, hexane was added after the reaction and the solution was cooled to 201C. Shiny needlelike orange crystals precipitated from the solution. The yield was W80%. The BSUA compound, a needlelike yellow solid, precipitated from the solution after re uxing the solution for 24 h under room light. The BSUA yield was W90%. UV/visible spectroscopy was used to investigate the reversible photo and thermal isomerization behaviors of TSUA and BSUA in solution (Fig. 13.2). For TSUA compound, emax was estimated to be 2.59 104 M 1 cm 1 on the basis of absorption band at 362 nm (the p p* transition of the trans isomer). UV irradiation with an Hg arc lamp (lmax = 350 nm) decreased the intensity of the 362-nm band and slightly increased the intensity of the 450-nm band, which is attributed to the n p* transition of the cis isomer. A photostationary state was reached within ca. 10 min. Exposure to room light caused the reverse cis-trans isomerization. Extended room light exposure (12 h) increased the trans isomer to ca. 96%. The cis2trans isomerization process was observed to be reversible over three cycles. In a detailed study, the rst-order kinetic constant of the cis-trans isomerization under room light exposure was estimated to be 1.75 10 4 s 1 for TSUA in ethanol solution at room temperature. Similar photoisomerization was observed for the BSUA compound in THF solution. UV irradiation (lmax = 350 nm) decreased the intensity of the 378-nm band (the p p* transition) and slightly increased the intensity of the 470-nm band (the n p* transition attributed



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int napms(int ms);

CORBA::Object_var poa_obj = orb->resolve_initial_references ("RootPOA"); PortableServer::POA_var poa = PortableServer::POA::_narrow (poa_obj);

napms(ms) ms is the number of milliseconds program execution pauses. It s an int value, therefore the maximum pause for any computer system depends on the size of an int. Negative values and 0 result in no pause, but do not produce an error.

(CH2)3-Si(OEt)3

Yeah, the name is cute: nap ms. Get it Still, namps is a popular typo. 1000 milliseconds equals 1 second. napms() is defined as a low-level NCurses function, one of the few documented in this appendix.





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This code essentially provides the server application with a reference to the root POA. The root POA is, as its name implies, the root of the POA hierarchy: other POAs can be created and retrieved via the reference to the root POA. More about the POA hierarchy and the INVOKER later. The ORB extensions themselves are represented as LOCAL OBJECTS, and their creation is typically triggered by the creation of the ORB core. LOCAL OBJECTS are represented by instances of regular C++ classes that have the same reference-passing semantics as remote objects, with the difference that they are not accessible remotely. They are registered internally to the ORB, so that CORBA applications can query for references to them in order to configure and use them. To avoid creating and initializing a POA in client applications that do not need one, the POA component can be created and initialized on the first lookup. Thus when a server application does the lookup of the root POA via ORB::resolve_initial_references, the POA is created lazily using the LAZY ACQUISITION pattern. The Component Configurator [SSRB00] pattern documents how components such as the POA can be loaded on demand. As the name Object Request Broker indicates, the ORB is responsible for brokering requests between object, as described in the BROKER pattern. There has always been some confusion around the term ORB:

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napms(500);

(CH2)3-Si(OEt)3

napms(60000);

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 #include <ncurses.h> int main(void) { initscr(); addstr( Give me a second... ); refresh(); napms(1000); addstr( ...Thanks!\n ); refresh(); getch(); endwin(); return 0; }

(CH2)3-Si(OEt)3

1. For a CORBA server, the POA is not an extension, but a necessary component. From a purely architectural perspective, however, the POA extends the ORB core with customizable dispatching functionality. For real-time systems, specialized POA implementations exist. 24.09.2004 21:13 c12.fm 0.3

Sample output:

(CH2)3-Si(OEt)3

...Thanks!

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