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are the angular frequencies of the incident radiation and the angular frequency with a transition from the initial state i of the Raman transition to any state I- of the unperturbed molecule, respectively. I;. is a damping factor related to the lifetime of the state I'. h = hi 271 with h being the Planck constant. Note, that the summation is over all states r of the unperturbed system, with the exclusion of i andf', the states between which the Raman transition takes place. The coordinate suffixes p and (T refer to the molecule-fixed Cartesian vectors .Y, and z . The interpretation of Eq. (6.1-1) is that Raman scattering is a two-photon process involving virtual absorption from the initial state i to the entire manifold of eigenstates of the unperturbed molecule, followed by virtual emission to the final state f . In the semiclassical approach, the molecule is described quantum mechanically, i. e. the polarizability tensor is calculated according to Eq. (6.1-l), whereas the electric field, the inducement of the dipole moment via the polarizability of the molecule as well as the dipole scattering itself are described using classical electrodynamics. The scattering of the induced dipole moment is therefore treated as that arising from an oscillating Hertzian dipole. Such approaches have been worked out in detail in several texts by Placzek (l934), Behringer and Brandmiiller ( 1 956), Behringer (1958), and by Albrecht (1961). Thus, the total intensity scattered into the solid angle 4n: at angular frequency ws(. w h ~ f (plus for anti-Stokes, minus for Stokes, wfi = angular frequency for Raman = g i transition from state i to state f ) on the average by one freely orientable molecule is given by (Behringer and Brandmuller, 1956)



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where the information amplitudes aI n , aQn independently range over the sets of equi probable values i = 2i 1 M , i = 1, 2, . . . , M, and l = 2l 1 M , l = 1, 2, . . . , M, respectively and the I and Q subscripts denote the inphase and quadrature channels. Here again because of the assumed rectangular pulse shape, the complex baseband signal S(t) = Ac aI n + j aQn is constant in this same interval. At the receiver the signal is again rst complex conjugate demodulated by cr (t), which results in x(t) = Ac aI n + j aQn + N (t) (3.7)

17.3-17.8 (R2)





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Importing images in Illustrator is called placing images. Select File Place... to bring up the Place dialog box, as shown in Figure 5.24. Make sure Link, Template, and Replace are unchecked. Link is the only one checked by default. Link creates a link to the original image. Link your images if you want changes to the original placed image to automatically appear in the Illustrator document. After the image is placed on the artboard, make sure you have the Selection tool chosen. The Selection tool is the black arrow. Use the Selection tool to resize the placed image. To resize the placed image while constraining proportions, do the following:

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Tumbling mills are commonly used in industry for grinding large quantities. There are three distinct types, each with different application areas: Ball mills are operated with cylpebs or balls, and often employ a conical shape or compartments for better milling characteristics; they can also be used for microfine milling. Rod mills rods of up to 6 m in length as the grinding media, and can be used for fine milling. Autogeneous mills use the grinding stock itself as grinding media, but can only be used for fine crushing. They have the lowest length to diameter (L/D) ratio of 0.25, whereas rod and ball mills can have a L/D ratio up to 6. The motion of the grinding media depends on the rotation speed, and can be cascading at low speeds (Fig. 14.7), cataracting at medium speed, and centrifugal at higher speeds. The volume fraction of the grinding media amounts to 0.3, while the mass fraction of the grinding stock is typically less than 0.2 of the total mass. Planetary mills operate at higher stress intensities than tumbling mills. Grinding drums are placed on a rotating bracket and rotate at about 400 rpm such that accelerations of 60 g and over are possible. These mills are used for nanofine milling in batch mode (Fig. 14.8).

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