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This reacts further with a third molecule of acetylene via a Diels-Alder reaction (through 7-metallanorbornadiene 13) or insertion. Experimental evidence74 ,75 favors the former the pathway. This mechanism is supported by the transformation of preformed metallacyclopentadienes with alkynes,73,76-78 and labeling experiments79 that excluded the involvement of cyclobutadiene intermediates. It also accounts for the observation that terminal alkynes yield 1,2,4- (and 1,3,5-) trisubstituted benzene derivatives as the main product but not 1,2,3 derivatives. In contrast with this picture in cyclotrimerization with PdCITbased catalysts, stepwise linear insertion of alkynes takes place without the involvement of palladacyclopentadiene. 8o Cyclotetramerization to form cyclooctatetraene occurs only with nicke1. 46 ,63,68 The best catalysts are octahedral Ni(II) complexes, such as bis(cyclooctatetraene) dinicke1. 46 Internal alkynes do not form cyclooctatetraene derivatives but participate in cooligomerization with acetylene. Of the possible mechanistic pathways, results with [1- 13 C]-acetylene 81 favor a stepwise insertion process or a concerted reaction, and exclude any symmetric intermediate (cyclobutadiene, benzene). The involvement of dinuclear species are in agreement with most observations. 46 ,82-84



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For the best results with area type, make the type small relative to the path and justify it by pressing Ctrl+Shift+J ( +Shift+J). This ensures that the type flows up against the edges of the path.

Estimated Hedge Fund Assets under Management ($Billions) Source: 2004 by Van Hedge Fund Advisors International, LLC, and/or its licensors, Nashville, TN, USA.

di(O)

2 T T T E{y1 } = E{w1 x1 xT w1 } = w1 Rx1 x1 w1 = w1 w1 = 1, 1

-3 -2 B -1 0 1 2 3 [m]

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A great feature of using Adobe Illustrator with Premiere is that Premiere translates the blank areas of the Illustrator file as an alpha channel mask. You can now import the flower files that you just created into Premiere and create the Flowers Everywhere project. In this project, the Bend video effect was applied to the background and the Bevel Alpha video effect was applied to the text in the top video track seen in Figure 13-19 (Video Track 3). Figure 13-20 shows frames from the Flowers Everywhere project. (You can access 13 files on the CD at the back of this book to create the Flowers Everywhere project.)

In contrast with other reagents, selective oxidation of methylcyclohexenes can also be achieved. Some reagents, such as Se02 (the best oxidant for allylic hydroxylation) and palladium(II) (best known for oxidation of alkenes to allylic alcohols and carbonyl compounds), can be used in the formation of ex,~-unsaturated carbonyl compounds under special reaction conditions. 671 ,692

The individual sections of the definition are as follows:

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Queries that cannot be displayed graphically do not allow parameter values to be accepted. For example, try using the SQL query shown here in the Microsoft Query program.

Options available in the Table Assistant are similar to options for creating tables in Adobe InDesign or Microsoft Excel. You can add rows and columns, apply shading to alternating rows, add headers and footers, and divide the table into sections. After creating a table, you can apply edits using the Table menu for adding and deleting rows and columns, merge and split cells, and distribute and group sections.

A text character can be included in custom formats to indicate millions (M) or thousands (K). For example, in the Number tab of the Format Cells dialog box, select the Custom category and enter a format like this:

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You can crop a frame down to 50 percent of the original dimensions. As you d imagine, quality suffers when you crop an image because the remaining data must appear

Given the network in Fig. 10.14 with the parameters Z s = 3 + j l n, jw L , = j 2 n, jw L, = j2 n, jw M = j l n, and Z L = I - j l n, determine the im pedance seen by the

The drawing used in the following exercise on drawing with a custom UCS, ab08-c.dwg, is in the Drawings folder on the DVD.

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